Home
Class 12
CHEMISTRY
The atomic structure of He^(+) arises du...

The atomic structure of `He^(+)` arises due to transition from `n_(2)` to `n_(1)` level. If `n_(1)+n_(2)` is 3 and `n_(2)-n_(1)` is 1. Find the `lambda` in nm of transition for this series in `He^(+)` in nm.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the wavelength (λ) of the transition from the n=2 to n=1 energy level in the He⁺ ion, we can follow these steps: ### Step 1: Identify the values of n1 and n2 We are given two equations: 1. \( n_1 + n_2 = 3 \) 2. \( n_2 - n_1 = 1 \) Let's solve these equations to find the values of \( n_1 \) and \( n_2 \). ### Step 2: Solve the equations From the second equation, we can express \( n_2 \) in terms of \( n_1 \): \[ n_2 = n_1 + 1 \] Now, substitute this expression into the first equation: \[ n_1 + (n_1 + 1) = 3 \] \[ 2n_1 + 1 = 3 \] \[ 2n_1 = 2 \] \[ n_1 = 1 \] Now substitute \( n_1 \) back to find \( n_2 \): \[ n_2 = n_1 + 1 = 1 + 1 = 2 \] Thus, we have: - \( n_1 = 1 \) - \( n_2 = 2 \) ### Step 3: Use Rydberg's formula For hydrogen-like ions, the Rydberg formula is given by: \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( R \) is the Rydberg constant (\( R = 1.1 \times 10^7 \, \text{m}^{-1} \)) - \( Z \) is the atomic number (for He, \( Z = 2 \)) - \( n_1 = 1 \) and \( n_2 = 2 \) ### Step 4: Substitute the values into the formula Substituting the known values into the Rydberg formula: \[ \frac{1}{\lambda} = 1.1 \times 10^7 \times 2^2 \left( \frac{1}{1^2} - \frac{1}{2^2} \right) \] \[ = 1.1 \times 10^7 \times 4 \left( 1 - \frac{1}{4} \right) \] \[ = 1.1 \times 10^7 \times 4 \left( \frac{3}{4} \right) \] ### Step 5: Simplify the expression \[ \frac{1}{\lambda} = 1.1 \times 10^7 \times 3 \] \[ = 3.3 \times 10^7 \, \text{m}^{-1} \] ### Step 6: Calculate λ Taking the reciprocal to find λ: \[ \lambda = \frac{1}{3.3 \times 10^7} \] \[ \lambda \approx 3.03 \times 10^{-8} \, \text{m} \] ### Step 7: Convert λ to nanometers To convert meters to nanometers, we multiply by \( 10^9 \): \[ \lambda \approx 3.03 \times 10^{-8} \, \text{m} \times 10^9 \] \[ \lambda \approx 30.3 \, \text{nm} \] ### Final Answer The wavelength of the transition from n=2 to n=1 in He⁺ is approximately **30.3 nm**. ---
Promotional Banner

Topper's Solved these Questions

  • NTA JEE MOCK TEST 96

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos
  • NTA JEE MOCK TEST 98

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos

Similar Questions

Explore conceptually related problems

The atomic spectrum of Li^(2+) arises due to the transition of an electron from n_(2) to n_(1) level. If n_(1) +n_(2) is 4 and n_(2)-n_(1) is 2, calculate the wavelength (in nm) of the transition for this series in Li^(2+)

The atomic spectrum of Li^(+2) ion arises due to the transition of an electron from n_(2) to n_(1) if n_(1) +n_(2)=4 and (n_(2)-n_(1)) =2 then the wavelength of 3^(rd) line of this series in Li^(+2) ion will be

The transition of an electron from n_(2)=5,6 ….. To n_(1) =4 gives rise to

Find the integral solution for n_(1)n_(2)=2n_(1)-n_(2), " where " n_(1),n_(2) in "integer" .

Electronic transition in He^(+) ion takes from n_(2) " to " n_(1) shell such that : 2n_(2)+3n_(1)=18 2n_(2)+3n_(1)=6 What will be the total number of photons emitted when electrons transit to n_(1) shell?

The wavelength of the first Balmer line caused by a transition from the n = 3 level to the n = 2 level in hydrogen is lamda_(1) . The wavelength of the line caused by an electronic transition from n = 5 to n = 3 is -

The wavelength of the first balmer line caused by a transition from the n = 3 level to the n = 2 level in hydrogen is lamda_(1) . The wavelength of the line caused by an electronic transition from n =5 to n =3 is

In hydrogen atom, electron makes transition from n = 4 to n = 1 level. Recoil momentum of the H atom will be

NTA MOCK TESTS-NTA JEE MOCK TEST 97-CHEMISTRY
  1. If DeltaG^(@)[HI(g)=-1.7kJ], the equilibrium constant for the reaction...

    Text Solution

    |

  2. 1 - Bromo -2, 2 - dimethylcyclohexane on treatment with methanol give...

    Text Solution

    |

  3. The major product P of the following reaction is

    Text Solution

    |

  4. In which of the following compounds hydrolysis tkes plcae through S(N^...

    Text Solution

    |

  5. The voltage of the cell consisting of Li(s) and F(2)(g) electrodes is ...

    Text Solution

    |

  6. The voltage the characteristics is not common between [Cu(en)(2)]^(2+)...

    Text Solution

    |

  7. AgBr(s)+2S(2)O(3)^(2-)(aq)hAq Ag(S(2)O(3))(2)^(3-)(aq)+Br^(-)(aq) Gi...

    Text Solution

    |

  8. The incorrect statement regarding above reactions is

    Text Solution

    |

  9. In the reaction shown below, identify the correct combination of te in...

    Text Solution

    |

  10. For adsorption of a gas on a solid, the plot of log (x//m) vs log P is...

    Text Solution

    |

  11. One of the hydrolysed product of the following compound does not react...

    Text Solution

    |

  12. In the reaction sequence C(6)H(5)-underset(O)underset(||)C-CH(3)overse...

    Text Solution

    |

  13. When A(2) and B(2) are allowed to react, the equilibrium constant of t...

    Text Solution

    |

  14. Arrange reactivity of given compounds in decreasing order for hydrolys...

    Text Solution

    |

  15. In the reaction x A rarr yB, log{-(d[A])/(dt)}=log{+(d[B])/(dt)}+0.3 T...

    Text Solution

    |

  16. Number of aldol products in the given reaction C(6)H(5) - CHO + CH(3...

    Text Solution

    |

  17. The atomic structure of He^(+) arises due to transition from n(2) to n...

    Text Solution

    |

  18. An alloy of Pb-Ag weighing 1.08g was dissolved in dilute HNO(3) and th...

    Text Solution

    |

  19. Consider the following ligands NH(2)^(-), acac, OH^(-), Gly, O(2)^(-),...

    Text Solution

    |

  20. The root mean square speed of N(2) molecules in sample at temperature ...

    Text Solution

    |