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The root mean square speed of N(2) molec...

The root mean square speed of `N_(2)` molecules in sample at temperature T is 'x'. If the temperature is doubled, then nitrogen molecules dissociate into atoms, the root mean square speedof nitrogen atoms becomes n times of 'x' find the value of n here?

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To solve the problem, we need to analyze the given information step by step. ### Step 1: Understand the root mean square speed formula The root mean square speed (vrms) of a gas is given by the formula: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] where: - \( R \) is the universal gas constant, - \( T \) is the temperature in Kelvin, - \( M \) is the molar mass of the gas. ### Step 2: Initial conditions We are given that the root mean square speed of \( N_2 \) molecules at temperature \( T \) is \( x \). Therefore, we can write: \[ x = \sqrt{\frac{3RT}{M_{N_2}}} \] ### Step 3: Doubling the temperature When the temperature is doubled, the new temperature \( T' \) becomes: \[ T' = 2T \] ### Step 4: Dissociation of nitrogen molecules When the nitrogen molecules dissociate into atoms, the molar mass changes. The molar mass of \( N_2 \) is \( M_{N_2} \), and when it dissociates into nitrogen atoms, the molar mass \( M' \) becomes: \[ M' = \frac{M_{N_2}}{2} \] ### Step 5: Calculate the new root mean square speed Now we can find the new root mean square speed \( v'_{rms} \) for nitrogen atoms at the new temperature: \[ v'_{rms} = \sqrt{\frac{3RT'}{M'}} = \sqrt{\frac{3R(2T)}{\frac{M_{N_2}}{2}}} \] This simplifies to: \[ v'_{rms} = \sqrt{\frac{3R(2T) \cdot 2}{M_{N_2}}} = \sqrt{\frac{6RT}{M_{N_2}}} \] ### Step 6: Relate new speed to initial speed We know that: \[ x = \sqrt{\frac{3RT}{M_{N_2}}} \] To express \( v'_{rms} \) in terms of \( x \): \[ v'_{rms} = \sqrt{2} \cdot \sqrt{\frac{3RT}{M_{N_2}}} = \sqrt{2} \cdot x \] ### Step 7: Find the value of \( n \) According to the problem, the new root mean square speed of nitrogen atoms becomes \( n \) times \( x \): \[ v'_{rms} = n \cdot x \] From our earlier calculation, we have: \[ \sqrt{2} \cdot x = n \cdot x \] Dividing both sides by \( x \) (assuming \( x \neq 0 \)): \[ n = \sqrt{2} \] ### Conclusion Thus, the value of \( n \) is: \[ \boxed{\sqrt{2}} \]
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