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No. of alpha-H atoms in the product (alk...

No. of `alpha-H` atoms in the product (alkene) formed when `(CH_(3))_(3)C CH(OH)CH_(3)` reacts with conc. `H_(2)SO_(4)`

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To determine the number of alpha-hydrogen atoms in the product (alkene) formed when (CH₃)₃C-CH(OH)CH₃ reacts with concentrated H₂SO₄, we can follow these steps: ### Step 1: Identify the structure of the starting compound The compound (CH₃)₃C-CH(OH)CH₃ can be drawn as follows: - The central carbon (C) is connected to a hydroxyl group (OH) and two methyl groups (CH₃). - The structure can be represented as: ``` CH₃ | CH₃-C-CH(OH)-CH₃ | CH₃ ``` ### Step 2: Reaction with concentrated H₂SO₄ When (CH₃)₃C-CH(OH)CH₃ reacts with concentrated sulfuric acid (H₂SO₄), the hydroxyl group (OH) is protonated to form a better leaving group (water, H₂O). This leads to the formation of a carbocation. ### Step 3: Formation of the carbocation The protonation of the hydroxyl group leads to the formation of a carbocation: - The carbocation is formed at the carbon that was attached to the hydroxyl group. - The structure of the carbocation can be represented as: ``` CH₃ | CH₃-C⁺-CH₃ | H ``` ### Step 4: Rearrangement of the carbocation To stabilize the carbocation, a methyl group can shift from an adjacent carbon to the positively charged carbon, leading to a more stable tertiary carbocation: - The rearrangement results in: ``` CH₃ | CH₃-C-CH₃ | CH₃ ``` ### Step 5: Elimination to form the alkene The next step is the elimination of a proton (H⁺) from a beta-carbon to form the double bond, resulting in the formation of an alkene: - The alkene formed will be: ``` CH₃ | CH₃-C=CH₂ | CH₃ ``` ### Step 6: Count the alpha-hydrogens Alpha-hydrogens are the hydrogens attached to the carbon atoms adjacent to the double bond (alkene): - In the alkene structure, we can see that: - The carbon adjacent to the double bond has 3 alpha-hydrogens (from the CH₃ group). - The other carbon adjacent to the double bond has 2 alpha-hydrogens (from the CH₂ group). Thus, the total number of alpha-hydrogens in the product is: - 3 (from one carbon) + 2 (from the other carbon) = 5 alpha-hydrogens. ### Final Answer The number of alpha-hydrogen atoms in the product (alkene) formed is **5**. ---
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