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2 mole of A (atomic weight =60 ) is tak...

2 mole of A (atomic weight =60 ) is taken in a 2 litre vessel which immediately comes into equilibrium with B as follows,
`A(g) hArr 2B(g)`
The density of the equilibrium mixture is

A

0.6 gm/L

B

0.06 gm/mL

C

3.6 gm/L

D

data insufficient

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The correct Answer is:
To find the density of the equilibrium mixture of gases A and B, we will follow these steps: ### Step 1: Determine the mass of A Given: - Moles of A = 2 moles - Atomic weight of A = 60 g/mol To calculate the mass of A: \[ \text{Mass of A} = \text{Moles} \times \text{Molecular Weight} = 2 \, \text{moles} \times 60 \, \text{g/mol} = 120 \, \text{grams} \] ### Step 2: Determine the mass of B From the reaction: \[ A(g) \rightleftharpoons 2B(g) \] For every 1 mole of A that reacts, 2 moles of B are produced. Since we start with 2 moles of A, we will produce: \[ \text{Moles of B} = 2 \times 2 = 4 \, \text{moles} \] ### Step 3: Calculate the mass of B Assuming B has the same atomic weight as A (as it is not given, we will consider it for calculation): - Atomic weight of B = 60 g/mol (for simplicity, we assume it is the same as A) To calculate the mass of B: \[ \text{Mass of B} = \text{Moles of B} \times \text{Molecular Weight} = 4 \, \text{moles} \times 60 \, \text{g/mol} = 240 \, \text{grams} \] ### Step 4: Calculate the total mass of the mixture The total mass of the equilibrium mixture is the sum of the masses of A and B: \[ \text{Total Mass} = \text{Mass of A} + \text{Mass of B} = 120 \, \text{grams} + 240 \, \text{grams} = 360 \, \text{grams} \] ### Step 5: Determine the volume of the mixture The volume of the vessel is given as: \[ \text{Volume} = 2 \, \text{liters} \] ### Step 6: Calculate the density of the mixture Density is defined as mass per unit volume: \[ \text{Density} = \frac{\text{Total Mass}}{\text{Volume}} = \frac{360 \, \text{grams}}{2 \, \text{liters}} = 180 \, \text{grams/liter} \] ### Final Answer The density of the equilibrium mixture is: \[ \text{Density} = 180 \, \text{grams/liter} \] ---
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