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The relationship between Kp and Kc is co...

The relationship between `K_p and K_c` is correctly shown as

A

`K_c =K_p (RT)^(Deltan)`

B

`K_p=K_c(RT)^(-Deltan)`

C

`K_p=K_c (RT)^(Deltan)`

D

`K_c=K_p(RT)^(-Deltan)`

Text Solution

AI Generated Solution

The correct Answer is:
To derive the relationship between \( K_p \) and \( K_c \), we will start with a general chemical reaction and then apply the definitions of these equilibrium constants. ### Step-by-Step Solution 1. **Write the General Reaction**: Consider a general reaction: \[ aA + bB \rightleftharpoons cC + dD \] 2. **Define \( K_c \)**: The equilibrium constant \( K_c \) is defined in terms of the concentrations of the products and reactants: \[ K_c = \frac{[C]^c[D]^d}{[A]^a[B]^b} \] 3. **Define \( K_p \)**: The equilibrium constant \( K_p \) is defined in terms of the partial pressures of the products and reactants: \[ K_p = \frac{(P_C)^c(P_D)^d}{(P_A)^a(P_B)^b} \] 4. **Relate Concentration and Pressure**: The relationship between concentration and partial pressure can be expressed using the ideal gas law: \[ P = CRT \] where \( C \) is the concentration, \( R \) is the ideal gas constant, and \( T \) is the temperature in Kelvin. 5. **Substituting for Partial Pressures**: Substitute the expressions for partial pressures in terms of concentrations into the equation for \( K_p \): \[ K_p = \frac{(C_C RT)^c (C_D RT)^d}{(C_A RT)^a (C_B RT)^b} \] 6. **Simplifying the Equation**: This can be simplified to: \[ K_p = \frac{[C]^c[D]^d (RT)^{c+d}}{[A]^a[B]^b (RT)^{a+b}} \] Rearranging gives: \[ K_p = K_c (RT)^{\Delta n} \] where \( \Delta n = (c + d) - (a + b) \) is the change in the number of moles of gas. 7. **Final Relationship**: Thus, the relationship between \( K_p \) and \( K_c \) can be expressed as: \[ K_p = K_c (RT)^{\Delta n} \] ### Conclusion The correct relationship between \( K_p \) and \( K_c \) is: \[ K_p = K_c (RT)^{\Delta n} \]
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