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Match Column-I with Column -II, {:("Co...

Match Column-I with Column -II,
`{:("Column -I","Column-II"),(A_2(g)+3B_2(g)hArr2AB_3(g),(RT)^(-2)),(A_2(g)+B_2(g)hArr2AB(g),(RT)^0),(A_2(s)+3/2B_2(g)hArrAB_3(g),(RT)^(1//2)),(AB_2(g)hArrAB(g)+1/2B_2(g),(RT)^(-1//2)),("","Favours forward reaction by rising pressure"):}`

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To solve the problem of matching Column-I with Column-II, we will analyze each reaction in Column-I and determine the corresponding value of \( (RT)^{\Delta n} \) in Column-II based on the change in the number of moles of gas during the reaction. ### Step-by-Step Solution: 1. **Identify the reactions and calculate \( \Delta n \)**: - For each reaction, we need to find \( \Delta n \), which is defined as: \[ \Delta n = n_p - n_r \] where \( n_p \) is the sum of the stoichiometric coefficients of the products (in gaseous phase) and \( n_r \) is the sum of the stoichiometric coefficients of the reactants (in gaseous phase). 2. **Reaction A**: \( A_2(g) + 3B_2(g) \rightleftharpoons 2AB_3(g) \) - Products: \( 2 \) moles of \( AB_3 \) (gaseous) → \( n_p = 2 \) - Reactants: \( 1 + 3 = 4 \) moles of \( A_2 \) and \( B_2 \) (gaseous) → \( n_r = 4 \) - \( \Delta n = 2 - 4 = -2 \) - Thus, \( K_p/K_c = (RT)^{-2} \). 3. **Reaction B**: \( A_2(g) + B_2(g) \rightleftharpoons 2AB(g) \) - Products: \( 2 \) moles of \( AB \) (gaseous) → \( n_p = 2 \) - Reactants: \( 1 + 1 = 2 \) moles of \( A_2 \) and \( B_2 \) (gaseous) → \( n_r = 2 \) - \( \Delta n = 2 - 2 = 0 \) - Thus, \( K_p/K_c = (RT)^{0} \). 4. **Reaction C**: \( A_2(s) + \frac{3}{2}B_2(g) \rightleftharpoons AB_3(g) \) - Products: \( 1 \) mole of \( AB_3 \) (gaseous) → \( n_p = 1 \) - Reactants: \( 0 + \frac{3}{2} = \frac{3}{2} \) moles of \( B_2 \) (gaseous) → \( n_r = \frac{3}{2} \) - \( \Delta n = 1 - \frac{3}{2} = -\frac{1}{2} \) - Thus, \( K_p/K_c = (RT)^{-1/2} \). 5. **Reaction D**: \( AB_2(g) \rightleftharpoons AB(g) + \frac{1}{2}B_2(g) \) - Products: \( 1 + \frac{1}{2} = \frac{3}{2} \) moles of \( AB \) and \( B_2 \) (gaseous) → \( n_p = \frac{3}{2} \) - Reactants: \( 1 \) mole of \( AB_2 \) (gaseous) → \( n_r = 1 \) - \( \Delta n = \frac{3}{2} - 1 = \frac{1}{2} \) - Thus, \( K_p/K_c = (RT)^{1/2} \). 6. **Determine which reactions favor the forward reaction by rising pressure**: - According to Le Chatelier's principle, increasing pressure favors the reaction that produces fewer moles of gas. - For Reaction A: \( 4 \) moles (reactants) → \( 2 \) moles (products) → Favors forward. - For Reaction B: \( 2 \) moles (reactants) → \( 2 \) moles (products) → No effect. - For Reaction C: \( \frac{3}{2} \) moles (reactants) → \( 1 \) mole (products) → Favors forward. - For Reaction D: \( 1 \) mole (reactants) → \( \frac{3}{2} \) moles (products) → Favors backward. ### Final Matches: - **A**: \( (RT)^{-2} \) - **B**: \( (RT)^{0} \) - **C**: \( (RT)^{-1/2} \) - **D**: \( (RT)^{1/2} \)
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