The section contains one question. Each question contains statements given in two columns which have to be matched . The statements in Column I are labelled A, B, C and D , while the statements in Column II are labelled p,q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statements (s) in Column II . The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example:
If the correct matches are A-p, s and t, B-q and r, C-p and q, and D-s and t, then the correct darkening of bubbles will look like the following .

Match the following :

The section contains one question. Each question contains statements given in two columns which have to be matched . The statements in Column I are labelled A, B, C and D , while the statements in Column II are labelled p,q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statements (s) in Column II . The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example:
If the correct matches are A-p, s and t, B-q and r, C-p and q, and D-s and t, then the correct darkening of bubbles will look like the following .

Match the following :

If the correct matches are A-p, s and t, B-q and r, C-p and q, and D-s and t, then the correct darkening of bubbles will look like the following .

Match the following :

Text Solution
Verified by Experts
The correct Answer is:
`A to (r, s), B to (q, t) , C to (p) D to (s, t)`
(A) `Na_(2)CO_(3) + NaHCO_(3)`
Using phenolphthalein indicator .
eq of `Na_(2)CO_(3)` will react.
` :. 1^(st)` titre value
`Na_(2) CO_(3) + HCl to NaHCO_(3)+ NaCl`
` :. 1^(st) ` titre value = eq of `Na_(2)CO_(3)`
Using methyl orange indicator :
eq of `NaHCO_(3) ` produced from `Na_(2)CO_(3)` & eq of `NaHCO_(3)` present will react :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
` :. 2^(nd) ` titre value = eq of `Na_(2)CO_(3) + " eq of " NaHCO_(3)` .
` A to r, s`
(B) `Na_(2)CO_(3) + NaOH`
Using phenolphthalein indicator :
`Na_(2)CO_(3)+HCl to NaHCO_(3) + NaCl`
` NaOH + HCl to NaCl + H_(2)O`
` :. 1^(st) ` titre value = eq of `Na_(2)CO_(3) + ` eq of NaOH .
Using methyl orange indicator :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
(produced from `Na_(2)CO_(3)`)
`2^(nd) ` titre value = eq of `Na_(2)CO_(3)`
` B to q,t `
(C ) `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4)`
Using `NaOH ` & phenolphthalein indicator :
` H_(2)C_(2)O_(4) + NaOH to Na_(2)C_(2)O_(4) + H_(2)O`
` :. 1^(st)` titre value of NaOH = eq. of `H_(2)C_(2)O_(4)`
Using `KMnO_(4)` in acidic medium :
Using `KMnO_(4)` in acidic medium :
`KMnO_(4) + Na_(2)C_(2)O_(4) + H^(+) to CO_(2) + Mn^(2+) + H_(2)O + Na^(+)`
`2^(nd)` titre value will give the eq of total `Na_(2)C_(2)O_(4) & H_(2)C_(2)O_(4)` but in different n-factor value .
The estimation of `Na_(2)C_(2)O_(4)` can be done by the difference in moles of total `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4) " in " 2^(nd) ` titration & moles of `H_(2)C_(2)O_(4) " in " 1^(st)` titration .
But difference in `1^(st) & 2^(nd)` titre value will not give the estimation of `1^(st)` constituent.
` C to P `
(D) `H_(2)CO_(3) + NaHCO_(3)`
Using NaOH & methyl orange indicator :
`H_(2)CO_(3) + NaOH to NaHCO_(3) + H_(2)O`
`1^(st)` titre value will give the estimation of `1^(st)` constituent.
Using `NaOH` & phenolphthalein indicator :
`NaHCO_(3) + NaOH to Na_(2)CO_(3) + H_(2)O`
`uparrow`
`(NaHCO_(3) " present + " NaHCO_(3) " preduced from " H_(2)CO_(3))`
Difference in `2^(nd) & 1^(st)` titre value will give the estimation of `2^(nd)` constituent .
`D to s, t`
Using phenolphthalein indicator .
eq of `Na_(2)CO_(3)` will react.
` :. 1^(st)` titre value
`Na_(2) CO_(3) + HCl to NaHCO_(3)+ NaCl`
` :. 1^(st) ` titre value = eq of `Na_(2)CO_(3)`
Using methyl orange indicator :
eq of `NaHCO_(3) ` produced from `Na_(2)CO_(3)` & eq of `NaHCO_(3)` present will react :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
` :. 2^(nd) ` titre value = eq of `Na_(2)CO_(3) + " eq of " NaHCO_(3)` .
` A to r, s`
(B) `Na_(2)CO_(3) + NaOH`
Using phenolphthalein indicator :
`Na_(2)CO_(3)+HCl to NaHCO_(3) + NaCl`
` NaOH + HCl to NaCl + H_(2)O`
` :. 1^(st) ` titre value = eq of `Na_(2)CO_(3) + ` eq of NaOH .
Using methyl orange indicator :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
(produced from `Na_(2)CO_(3)`)
`2^(nd) ` titre value = eq of `Na_(2)CO_(3)`
` B to q,t `
(C ) `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4)`
Using `NaOH ` & phenolphthalein indicator :
` H_(2)C_(2)O_(4) + NaOH to Na_(2)C_(2)O_(4) + H_(2)O`
` :. 1^(st)` titre value of NaOH = eq. of `H_(2)C_(2)O_(4)`
Using `KMnO_(4)` in acidic medium :
Using `KMnO_(4)` in acidic medium :
`KMnO_(4) + Na_(2)C_(2)O_(4) + H^(+) to CO_(2) + Mn^(2+) + H_(2)O + Na^(+)`
`2^(nd)` titre value will give the eq of total `Na_(2)C_(2)O_(4) & H_(2)C_(2)O_(4)` but in different n-factor value .
The estimation of `Na_(2)C_(2)O_(4)` can be done by the difference in moles of total `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4) " in " 2^(nd) ` titration & moles of `H_(2)C_(2)O_(4) " in " 1^(st)` titration .
But difference in `1^(st) & 2^(nd)` titre value will not give the estimation of `1^(st)` constituent.
` C to P `
(D) `H_(2)CO_(3) + NaHCO_(3)`
Using NaOH & methyl orange indicator :
`H_(2)CO_(3) + NaOH to NaHCO_(3) + H_(2)O`
`1^(st)` titre value will give the estimation of `1^(st)` constituent.
Using `NaOH` & phenolphthalein indicator :
`NaHCO_(3) + NaOH to Na_(2)CO_(3) + H_(2)O`
`uparrow`
`(NaHCO_(3) " present + " NaHCO_(3) " preduced from " H_(2)CO_(3))`
Difference in `2^(nd) & 1^(st)` titre value will give the estimation of `2^(nd)` constituent .
`D to s, t`
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This section contains 2 questions. Each questions contains statements given in two columns, which have to be matched. The statements in Column I are labelled A, B, C and D, while the statements in Column II are labelled p, q, r, s and t. Any given statement in Column I can have correct matching with one or more statement(s) in Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example : If the correct matches are A – p, s and t, B – q and r , C – p and q, and D – s and t, then the correct darkening of bubbles will look like the following Column II gives certain systems undergoing a process. Column I suggests changes in some of the parameters related to the system. Match the statements in Column I to the appropriate process(es) from Column II.
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