Home
Class 12
CHEMISTRY
Which is the correct expression that rel...

Which is the correct expression that relates changes of entropy with the change of pressure for an ideal gas at constant temperature, among the following?

A

`DeltaS = nRT ln P_(2)`

B

`DeltaS =T(P_(2)-P_(1))`

C

`DeltaS = nRln P_(1)/P_(2)`

D

`DeltaS = 2.303 nR ln P_(1)/P_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`DeltaE =q.w rArr 0 = q-w = pDeltaw`
`ds =d/T =(pDeltav)/T rArr ds = nR(dV)/V`
on integration `DeltaS = nR ln V_(2)/V_(1) = nR ln (P_(1)/P_(2))`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS AND THERMOCHEMISTRY

    FIITJEE|Exercise SOLVED PROBLEMS (OBJECTIVE) (REASONING TYPE QUESTIONS)|4 Videos
  • THERMODYNAMICS AND THERMOCHEMISTRY

    FIITJEE|Exercise SOLVED PROBLEMS (OBJECTIVE) (COMPREHENSION )|5 Videos
  • THERMODYNAMICS AND THERMOCHEMISTRY

    FIITJEE|Exercise SOLVED PROBLEM (SUBJECTIVE)|13 Videos
  • TEST PAPERS

    FIITJEE|Exercise CHEMISTRY|747 Videos
  • TRANSITION ELEMENTS & COORDINATION COMPOUNDS

    FIITJEE|Exercise MATCHIG LIST TYPE QUESTIONS|1 Videos

Similar Questions

Explore conceptually related problems

Which of the following expression represents correctly the variation of density of an ideal gas with change in temperature ?

Which of the following expressions are correct for an ideal gas ?

Which of the following expression for entropy change of an irreversible process ?

Which of the following relation is correct for an ideal gas ?

FIITJEE-THERMODYNAMICS AND THERMOCHEMISTRY -SOLVED PROBLEMS (OBJECTIVE)
  1. If an endothermic reaction is non-spontaneous at freezing point of wat...

    Text Solution

    |

  2. If the pressure and density of CO(2) gas in adiabatic process changes ...

    Text Solution

    |

  3. Which is the correct expression that relates changes of entropy with t...

    Text Solution

    |

  4. The bond energies of C=C and C-C at 298 K are 590 and 331 kJ mol^(-1),...

    Text Solution

    |

  5. A 3 mole sample of a triatomic ideal gas at 300 K is allowed to expand...

    Text Solution

    |

  6. If a gas absorbs 200J of heat and expands by 500 cm^(3) against a cons...

    Text Solution

    |

  7. The densities of graphite and diamond at 298 K are 3.31 g//cm^(3), res...

    Text Solution

    |

  8. For the process H(2)O(l) (1 "bar", 373 K) rarr H(2)O(g) (1"bar", 373 K...

    Text Solution

    |

  9. The value of log(10)K for a reaction A hArr B is (Given: Delta(f)H(298...

    Text Solution

    |

  10. Smelting of iron ore takes place through this reaction 2Fe(2)O(3)(s)...

    Text Solution

    |

  11. (1) For the given heat of reaction, (i) C(s)+O(2)(g)=CO(2)(g)+97 kca...

    Text Solution

    |

  12. What is the amount of heat to be supplied to prepare 128g of CaCO(3) b...

    Text Solution

    |

  13. Ionisation energy of A1=5137KJmol^(-1)(DeltaH) hydration of Al^(3+)=-4...

    Text Solution

    |

  14. At 0^(@)C , ice and water are in equilibrium and DeltaS and DeltaG for...

    Text Solution

    |

  15. 5 mol of an ideal gas expand reversibly from a volume of 8 dm^(3) to 8...

    Text Solution

    |

  16. What is value of DeltaU for reversible isothermal evaporation of 90g w...

    Text Solution

    |

  17. Which of the following statements is/are correct?

    Text Solution

    |

  18. The heat change accompanying the reaction 2H(2)(g)+O(2)(g) to 2H(2)O...

    Text Solution

    |

  19. The enthalpy change for the process C("graphite") rarr C(g)is called

    Text Solution

    |

  20. Enthalpy change equal internal energy change when

    Text Solution

    |