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Consider the following reactions. DeltaH...

Consider the following reactions. `DeltaH^(@)` values of the reactions hve been given as `-x, -y` and z kJ.
`Fe_(3)O_(4)(s) to 3Fe(s) + 2O_(2)(g), DeltaH^(@) = z kJ`
`2Fe(s) + O_(2)(g) to 2FeO(s), DeltaH^(@) =-x kJ`
`4Fe(s) + 3O_(2)(g) to 2Fe_(2)O_(3)(s), DeltaH^(@) =-y kJ`
In the given set of reaction, `-x//2` kJ refers to

A

Heat of formation of FeO(s)

B

Standard heat of formation of FeO(s)

C

Half the heat of formation of FeO(s)

D

All of these are correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reactions and understand what the term `-x/2` refers to in the context of thermodynamics, specifically in relation to standard enthalpy changes. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Enthalpy Changes**: - The first reaction is: \[ \text{Fe}_3\text{O}_4(s) \rightarrow 3\text{Fe}(s) + 2\text{O}_2(g), \quad \Delta H^\circ = z \, \text{kJ} \] - The second reaction is: \[ 2\text{Fe}(s) + \text{O}_2(g) \rightarrow 2\text{FeO}(s), \quad \Delta H^\circ = -x \, \text{kJ} \] - The third reaction is: \[ 4\text{Fe}(s) + 3\text{O}_2(g) \rightarrow 2\text{Fe}_2\text{O}_3(s), \quad \Delta H^\circ = -y \, \text{kJ} \] 2. **Understanding Standard Enthalpy of Formation**: - The standard enthalpy of formation (\(\Delta H_f^\circ\)) is defined as the change in enthalpy when one mole of a compound is formed from its elements in their standard states. - In this context, the reaction \(2\text{Fe}(s) + \text{O}_2(g) \rightarrow 2\text{FeO}(s)\) indicates that the formation of 2 moles of FeO from its elements releases \(-x\) kJ. Therefore, the formation of 1 mole of FeO would release \(-x/2\) kJ. 3. **Conclusion**: - The term \(-x/2\) kJ refers to the standard enthalpy of formation of 1 mole of FeO from its elements in their standard states. Thus, it can be denoted as: \[ \Delta H_f^\circ \text{ of FeO} = -\frac{x}{2} \, \text{kJ} \] ### Final Answer: The value of \(-\frac{x}{2}\) kJ refers to the standard enthalpy of formation of FeO(s) from its elements.

To solve the problem, we need to analyze the given reactions and understand what the term `-x/2` refers to in the context of thermodynamics, specifically in relation to standard enthalpy changes. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Enthalpy Changes**: - The first reaction is: \[ \text{Fe}_3\text{O}_4(s) \rightarrow 3\text{Fe}(s) + 2\text{O}_2(g), \quad \Delta H^\circ = z \, \text{kJ} ...
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