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Current efficiency is defined as the ext...

Current efficiency is defined as the extent of a desired electrochemical reaction, divided by the theoretical extent of the reaction times 100%. What is the current efficiency of an electrodeposition of Cy metal in which 9.8g Cu is deposited by passage of 3A current for 10000 seconds.

A

0.009

B

0.499

C

0.991

D

0.511

Text Solution

Verified by Experts

The correct Answer is:
C

`9.8g Cu=(9.8)/(63.5) xx 2=0.308" mol e"^(-1)`
`1000 xx 3 xx 1/(96500)=0.311" mol e"^(-1)`
If 0.311 mol electrons provided by the current 0.308 mol was used to deposit copper. The current efficiency is `(0.308)/(0.311) xx 100 =99.1%`
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