Home
Class 12
CHEMISTRY
The conductivity of 0.02 N solution of a...

The conductivity of 0.02 N solution of a cell of KCl at `25^@C" is "2.765 xx 10^(-3) Scm^(-1)`. If the resistance of a cell containing this solution is 4000 ohm, what will be the cell constant?

A

`11.06 cm^(-1)`

B

`1.21 cm^(-1)`

C

`1.19 cm^(-1)`

D

`1.286cm^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the cell constant of the KCl solution, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the given values**: - Conductivity (κ) = \(2.765 \times 10^{-3} \, \text{S/cm}\) - Resistance (R) = \(4000 \, \Omega\) 2. **Understand the relationship between resistance, conductivity, and cell constant**: The relationship can be expressed as: \[ R = \frac{1}{\kappa} \times \frac{L}{A} \] where \(L\) is the length of the cell and \(A\) is the cross-sectional area. The term \(\frac{L}{A}\) is defined as the cell constant (K). 3. **Rearranging the formula to find the cell constant**: From the equation, we can rearrange it to find the cell constant (K): \[ K = R \times \kappa \] 4. **Substituting the values into the formula**: Substitute the values of R and κ into the equation: \[ K = 4000 \, \Omega \times 2.765 \times 10^{-3} \, \text{S/cm} \] 5. **Calculating the cell constant**: \[ K = 4000 \times 2.765 \times 10^{-3} = 11.06 \, \text{cm}^{-1} \] ### Final Answer: The cell constant (K) is \(11.06 \, \text{cm}^{-1}\). ---

To find the cell constant of the KCl solution, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the given values**: - Conductivity (κ) = \(2.765 \times 10^{-3} \, \text{S/cm}\) - Resistance (R) = \(4000 \, \Omega\) ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    FIITJEE|Exercise Matrix -Match Type|1 Videos
  • ELECTROCHEMISTRY

    FIITJEE|Exercise Matrix -List Type Question|1 Videos
  • ELECTROCHEMISTRY

    FIITJEE|Exercise Solved Problems (Subjective)|25 Videos
  • CONCEPT OF ACIDS AND BASES

    FIITJEE|Exercise SINGLE INTEGER ANSWER TYPE QUESTIONS|4 Videos
  • ELECTROPHILIC AROMATIC SUBSTITUTION

    FIITJEE|Exercise NUMERICAL BASED QUESTIONS INDICATED BY DIGITAL INTERGER|1 Videos

Similar Questions

Explore conceptually related problems

The specific conductance of N/50 solution of KCl at 25^(@)C is 0.2765 "ohm"^(-1) . If the resistance of the cell containing this solution is 400 ohms , then the cell constant is

The specific conductivity of N/10 KCl solution at 20^(@)C is 0.0212 ohm^(-1) cm^(-1) and the resistance of the cell containing this solution at 20^(@)C is 55 ohm. The cell constant is :

Specific conductance of a decinormal solution of KCl is 0.0112 ohm^(-1) cm^(-1) . The resistance of a cell containing the solution was found to be 56. What is the cell constant ?

FIITJEE-ELECTROCHEMISTRY-Solved Problems (Objective)
  1. Cu^(+) + e rarr Cu, E^(@) = X(1) volt, Cu^(2+) + 2e rarr Cu, E^(@) =...

    Text Solution

    |

  2. If E(Fe^(2+)//Fe)^(@)=-0.440 V and E(Fe^(3+)//Fe^(2+))^(@)=0.770 V, th...

    Text Solution

    |

  3. The conductivity of 0.02 N solution of a cell of KCl at 25^@C" is "2.7...

    Text Solution

    |

  4. The resistance of 0.1 N solution of a salt is found to be 2.5xx10^(3) ...

    Text Solution

    |

  5. The equivalent conductance of monobasic acid at infinite dilution is 4...

    Text Solution

    |

  6. A current of 0.20A is passed for 482 s through 50.0mL of 0.100 M NaCl....

    Text Solution

    |

  7. Calculate the standard free energy change in kJ for the reaction Cu^(+...

    Text Solution

    |

  8. The standard reduction potential values of three metallic cation X, Y,...

    Text Solution

    |

  9. Consider the cell Zn|Zn^(2+) || Cu^(2+)|Cu. If the concentration of Z...

    Text Solution

    |

  10. The cell reaction as written is spontaneous if the cell potential is:

    Text Solution

    |

  11. Calculate the standard potential of the cell ,If the standard electrod...

    Text Solution

    |

  12. Given E(M^(4+),M^(3+))^(0)=xV, E(M^(4+),M)^(0)="y V hence "E(M^(3+),M)...

    Text Solution

    |

  13. Electrolysis of a concentrated aquoous solution of NaCl botween two Pt...

    Text Solution

    |

  14. The products of electrolysis of CuSO4(aq) between two Pt electrodes

    Text Solution

    |

  15. Which are true for a standard hydrogen electrode ?

    Text Solution

    |

  16. For the cell Ti|Ti^(+) (0.001 M)|Cu^(2+)(0.1 M)|Cu. E("cell")" at "256...

    Text Solution

    |

  17. A lead storage battery used in automobiles is

    Text Solution

    |

  18. Identify the correct statements:

    Text Solution

    |

  19. As dillution takes place

    Text Solution

    |

  20. For the reduction of NO(3)^(-) ion in an aqueous solution, is +0.96V...

    Text Solution

    |