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Mohr's salt is...

Mohr's salt is

A

`FeS_(2).7H_(2)O`

B

`FeSO_(4)(NH_(4))_(2)SO_(4).6H_(2)O`

C

`Fe_(2)(SO_(4))_(3)(NH_(4))_(2)SO_(4).24H_(2)O`

D

`K_(2)SO_(4).Fe_(2)(SO_(4))_(3).24H_(2)O`

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### Step-by-Step Solution: 1. **Definition of Mohr's Salt**: - Mohr's salt is an inorganic compound that is classified as a double salt. It is composed of two different cations and two different anions. 2. **Chemical Formula**: - The chemical formula for Mohr's salt is \( \text{(NH}_4)_2\text{Fe(SO}_4)_2 \cdot 6\text{H}_2\text{O} \). This indicates that it contains ammonium ions, iron(II) ions, sulfate ions, and water of crystallization. 3. **Ionic Composition**: - In the formula, you can identify: - Two ammonium ions (\( \text{NH}_4^+ \)) - One iron ion (\( \text{Fe}^{2+} \)) - Two sulfate ions (\( \text{SO}_4^{2-} \)) - Six water molecules (\( 6\text{H}_2\text{O} \)) 4. **Properties**: - Mohr's salt is known for its use in analytical chemistry, particularly in redox titrations and as a source of iron(II) ions. 5. **Identification of Mohr's Salt**: - When dissolved in water, Mohr's salt dissociates into its constituent ions, which can be detected in solution. 6. **Conclusion**: - Therefore, Mohr's salt is a double salt with the formula \( \text{(NH}_4)_2\text{Fe(SO}_4)_2 \cdot 6\text{H}_2\text{O} \).
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STATEMENT-1 : The equivalent mass of Mohr's salt is (M)/(4) [If M is molecular mass of Mohr's salt] and STATEMENT-2: The normality of Mohr's salt is higher than molarity for same amount and volume at constant temperature.

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is:

Mohrs salt is used as a Primary standard in the permanganometric titrations because

The mass of potassium dichromate crystal required to oxidise 750 cm^(3) of 0.6 M Mohr's salt solution is (molar mass=392)

KMnO_4 is prepared from the mineral pyrolusite, MnO_2 (deep purple colour). It acts as an oxidising agent in the neutral, alkaline as well as acidic medium in acidic medium it is used in volumetric analysis for estimation of Fe^(2+) , Cr_2O_4^(2-) salts etc. The titrations are carried out in presence of H_2SO_4 . However, before using it as a titrant, it is first standardised with standard oxalic acid solution or Mohr's salt solution . In one of the experiments on titration 26.8g of dry pure sodium oxalate (Mw=123gmol^-1) was dissolved in 1L of distilled water and then 100 mL of 2MH_2SO_4 were added. The solution was cooled. Now to this solution 0.1MKMnO_4 solution was added till a very faint pink colour persisted. Q. Mohr's salt, FeSO_4(NH_4)_2SO_46H_2O , is preffered over FeSO_4.7H_2O for standardisation of KMnO_4 solution because.

KMnO_4 is prepared from the mineral pyrolusite, MnO_2 (deep purple colour). It acts as an oxidising agent in the neutral, alkaline as well as acidic medium in acidic medium it is used in volumetric analysis for estimation of Fe^(2+) , Cr_2O_4^(2-) salts etc. The titrations are carried out in presence of H_2SO_4 . However, before using it as a titrant, it is first standardised with standard oxalic acid solution or Mohr's salt solution . In one of the experiments on titration 26.8g of dry pure sodium oxalate (Mw=123gmol^-1) was dissolved in 1L of distilled water and then 100 mL of 2MH_2SO_4 were added. The solution was cooled. Now to this solution 0.1MKMnO_4 solution was added till a very faint pink colour persisted. Q. The purple colour of KMnO_4 is due to

KMnO_4 is prepared from the mineral pyrolusite, MnO_2 (deep purple colour). It acts as an oxidising agent in the neutral, alkaline as well as acidic medium in acidic medium it is used in volumetric analysis for estimation of Fe^(2+) , Cr_2O_4^(2-) salts etc. The titrations are carried out in presence of H_2SO_4 . However, before using it as a titrant, it is first standardised with standard oxalic acid solution or Mohr's salt solution . In one of the experiments on titration 26.8g of dry pure sodium oxalate (Mw=123gmol^-1) was dissolved in 1L of distilled water and then 100 mL of 2MH_2SO_4 were added. The solution was cooled. Now to this solution 0.1MKMnO_4 solution was added till a very faint pink colour persisted. Q. When pyrolusite is fused with KOH and KClO_3 , we get

KMnO_4 is prepared from the mineral pyrolusite, MnO_2 (deep purple colour). It acts as an oxidising agent in the neutral, alkaline as well as acidic medium in acidic medium it is used in volumetric analysis for estimation of Fe^(2+) , Cr_2O_4^(2-) salts etc. The titrations are carried out in presence of H_2SO_4 . However, before using it as a titrant, it is first standardised with standard oxalic acid solution or Mohr's salt solution . In one of the experiments on titration 26.8g of dry pure sodium oxalate (Mw=123gmol^-1) was dissolved in 1L of distilled water and then 100 mL of 2MH_2SO_4 were added. The solution was cooled. Now to this solution 0.1MKMnO_4 solution was added till a very faint pink colour persisted. Q. The volume of KMnO_4 solution that must have been added to obtain the faint pink colour at the end point must be

FIITJEE-TRANSITION ELEMENTS & COORDINATION COMPOUNDS-ASSIGNMENT PROBLEMS (OBJECTIVE)(Level- I)
  1. In the dichromate dianion,

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  2. Which of the following transition metal ions is colourless ?

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  3. Mohr's salt is

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  4. If a compound absorbs violet colour from light, it will be

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  5. If orange-red colour is absorbed from white light, the observed colour...

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  6. Which transition elements exhibit +8 oxidation state

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  7. Colour in transition metal compounds is due to

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  8. In acidic solution, KMnO(4)is reduced to

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  9. The outermost shell electronic configuration 3d^(5), 4s^(2) represents

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  10. Maximum paramagnetism in 3d series is shown by

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  11. The stable oxidation states of Mo are

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  12. Which of the following character is not shown by the transition metals

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  13. Amongst the following, the lowest degree of paramgnetism per mole of t...

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  14. Which of the following has maximum number of unpaired electrons?

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  15. Compound that is both paramagnetic and coloured is:

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  16. Which of the following compound is expected to be coloured

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  17. If the configuration of manganese is [Ar]3d^(5),4s^(2), then maximum o...

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  18. Which type of bond is formed by transition metal with a metal ligand, ...

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  19. Which of the following ion is likely to form white complexes

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  20. Transition elements should be more reactive than hydrogen on the basis...

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