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When sucrose is heated with conc. HNO(3)...

When sucrose is heated with conc. `HNO_(3)` acid the product is

A

Saccharic acid

B

Oxalic acid

C

Formic acid

D

Invert sugar

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product formed when sucrose is heated with concentrated nitric acid (HNO3), we can follow these steps: ### Step-by-Step Solution: 1. **Identify Sucrose**: Sucrose is a disaccharide composed of glucose and fructose. Its chemical formula is C12H22O11. 2. **Understand the Reaction**: Concentrated nitric acid (HNO3) acts as an oxidizing agent. When sucrose is heated with HNO3, it undergoes oxidation. 3. **Oxidation Process**: During the oxidation process, the hydroxyl groups (–OH) in sucrose can be oxidized, leading to the formation of carboxylic acids. 4. **Identify the Products**: The primary product of the oxidation of sucrose with concentrated HNO3 is oxalic acid (C2H2O4). Additionally, nitrogen dioxide (NO2) gas is released, along with water (H2O). 5. **Write the Balanced Reaction**: The overall reaction can be summarized as: \[ C_{12}H_{22}O_{11} + HNO_3 \rightarrow C_2H_2O_4 + NO_2 + H_2O \] This indicates that one mole of sucrose reacts with nitric acid to produce oxalic acid, nitrogen dioxide, and water. 6. **Conclusion**: Therefore, the product formed when sucrose is heated with concentrated HNO3 is oxalic acid. ### Final Answer: The product is **oxalic acid (C2H2O4)**. ---
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