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The rate constant of a reaction has same...

The rate constant of a reaction has same units as the rate of reaction. The reaction is of:

A

zero order

B

first order

C

second order

D

none of these

Text Solution

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The correct Answer is:
To determine the type of reaction for which the rate constant has the same units as the rate of reaction, we will analyze the different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: The rate of a reaction is generally expressed in terms of concentration change per unit time, typically in units like mol/L/s (molarity per second). 2. **Zero-Order Reaction**: - In a zero-order reaction, the rate of reaction is independent of the concentration of the reactants. - The rate law can be expressed as: \[ \text{Rate} = k \] - Here, \( k \) is the rate constant. - Since the rate does not depend on concentration, the units of \( k \) must be the same as the units of the rate of reaction. - Therefore, for a zero-order reaction, the units of the rate constant \( k \) are the same as the rate of reaction, which is mol/L/s. 3. **First-Order Reaction**: - In a first-order reaction, the rate is directly proportional to the concentration of one reactant. - The rate law can be expressed as: \[ \text{Rate} = k[A] \] - Here, the units of \( k \) would be different because the rate has units of mol/L/s, and \( [A] \) has units of mol/L. Thus, the units of \( k \) would be: \[ \text{Units of } k = \frac{\text{mol/L/s}}{\text{mol/L}} = \text{s}^{-1} \] - Therefore, the units of the rate constant \( k \) are not the same as the rate of reaction. 4. **Second-Order Reaction**: - In a second-order reaction, the rate is proportional to the square of the concentration of one reactant. - The rate law can be expressed as: \[ \text{Rate} = k[A]^2 \] - The units of \( k \) in this case would be: \[ \text{Units of } k = \frac{\text{mol/L/s}}{(\text{mol/L})^2} = \text{L/mol/s} \] - Again, the units of the rate constant \( k \) are not the same as the rate of reaction. 5. **Conclusion**: - The only reaction type where the rate constant \( k \) has the same units as the rate of reaction is the **zero-order reaction**. ### Final Answer: The reaction is of **zero order**. ---

To determine the type of reaction for which the rate constant has the same units as the rate of reaction, we will analyze the different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: The rate of a reaction is generally expressed in terms of concentration change per unit time, typically in units like mol/L/s (molarity per second). 2. **Zero-Order Reaction**: ...
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