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t(1//2) of C^(14) isotope is 5770 years...

`t_(1//2)` of `C^(14)` isotope is 5770 years. time after which 72% of isotope left is:

A

2740 years

B

274 years

C

2780 years

D

278 years

Text Solution

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The correct Answer is:
To solve the problem of determining the time after which 72% of the C-14 isotope is left, we can follow these steps: ### Step 1: Understanding the Half-Life The half-life (t₁/₂) of C-14 is given as 5770 years. This means that every 5770 years, half of the remaining C-14 will decay. ### Step 2: Determine the Remaining Percentage If 72% of the isotope is left, then the percentage that has decayed is: \[ 100\% - 72\% = 28\% \] This means that 28% of the original C-14 has decayed. ### Step 3: Calculate the Rate Constant (k) For a first-order reaction, the relationship between the half-life and the rate constant (k) is given by: \[ k = \frac{0.693}{t_{1/2}} \] Substituting the half-life of C-14: \[ k = \frac{0.693}{5770 \text{ years}} \] Calculating this gives: \[ k \approx 1.202 \times 10^{-4} \text{ years}^{-1} \] ### Step 4: Use the First-Order Kinetics Equation The first-order kinetics equation is: \[ t = \frac{2.303}{k} \log\left(\frac{[A]_0}{[A]_t}\right) \] Where: - \([A]_0\) is the initial concentration (100%), - \([A]_t\) is the concentration at time t (72%). ### Step 5: Substitute Values into the Equation Substituting the values into the equation: \[ t = \frac{2.303}{1.202 \times 10^{-4}} \log\left(\frac{100}{72}\right) \] ### Step 6: Calculate the Logarithm First, calculate the logarithm: \[ \log\left(\frac{100}{72}\right) \approx \log(1.3889) \approx 0.143 \] ### Step 7: Calculate Time (t) Now substitute the log value back into the equation: \[ t = \frac{2.303}{1.202 \times 10^{-4}} \times 0.143 \] Calculating this gives: \[ t \approx 2742 \text{ years} \] ### Final Answer Thus, the time after which 72% of the C-14 isotope is left is approximately **2740 years**. ---
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