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The equivalent conductance of 0.001 M ac...

The equivalent conductance of `0.001` M acetic acid is `50 " ohm"^(-1)cm^(2)eq^(-1)`. The maximum value of equivalent conductance is 250 `"ohm"^(-1) cm^(2) eq^(-1)`.What is its degree of ionization?

A

`0.2%`

B

`2%`

C

`20%`

D

`40%`

Text Solution

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The correct Answer is:
To find the degree of ionization of acetic acid, we can use the formula for degree of ionization (α): \[ \alpha = \frac{\Lambda_m}{\Lambda_m^0} \] where: - \(\Lambda_m\) is the equivalent conductance at the given concentration, - \(\Lambda_m^0\) is the maximum equivalent conductance. **Step-by-step solution:** 1. **Identify the given values:** - Equivalent conductance (\(\Lambda_m\)) = 50 ohm\(^{-1}\)cm\(^2\)eq\(^{-1}\) - Maximum equivalent conductance (\(\Lambda_m^0\)) = 250 ohm\(^{-1}\)cm\(^2\)eq\(^{-1}\) 2. **Substitute the values into the formula:** \[ \alpha = \frac{50}{250} \] 3. **Calculate the degree of ionization:** \[ \alpha = \frac{50}{250} = \frac{1}{5} = 0.2 \] 4. **Convert the degree of ionization to percentage:** \[ \text{Percentage of ionization} = \alpha \times 100 = 0.2 \times 100 = 20\% \] 5. **Final answer:** The degree of ionization of acetic acid is 20%. ---
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