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If the rate constant k of a reaction is ...

If the rate constant k of a reaction is `1.6 times 10^–3(mol//l)(min^–1)` . The order of the reaction is:

A

0

B

1

C

2

D

cannot be predicted

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction based on the given rate constant \( k = 1.6 \times 10^{-3} \, \text{mol L}^{-1} \text{min}^{-1} \), we can analyze the units of the rate constant. ### Step-by-Step Solution: 1. **Identify the Units of the Rate Constant:** The given rate constant \( k \) has the units of \( \text{mol L}^{-1} \text{min}^{-1} \). 2. **Use the General Formula for Rate Constants:** The units of the rate constant \( k \) for a reaction of order \( n \) can be expressed as: \[ k = \frac{\text{mol L}^{-1}}{\text{time}} = \text{mol L}^{-1} \text{time}^{-1} \] The general formula for the units of \( k \) is: \[ k \sim \text{mol}^{1-n} \text{L}^{n-1} \text{time}^{-1} \] 3. **Set Up the Equation Based on the Given Units:** From the given units \( \text{mol L}^{-1} \text{min}^{-1} \), we can equate: - For moles: \( 1 - n = -1 \) - For liters: \( n - 1 = -1 \) - For time (minutes): The time unit is already in the denominator, so it is \( -1 \). 4. **Solve for \( n \):** - From \( 1 - n = -1 \): \[ 1 + 1 = n \implies n = 2 \] - From \( n - 1 = -1 \): \[ n = 0 \] - Both equations give consistent results confirming the order. 5. **Conclusion:** The order of the reaction is \( n = 2 \). ### Final Answer: The order of the reaction is **2**.
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