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The temperature coefficient of a reactio...

The temperature coefficient of a reaction is :

A

The ratio of the rate constants of two reactions at `25^@C`

B

The ratio of the rate constants of a reaction at `25^@C and 35^@C`

C

The ratio of the rate constants at any two different temperature

D

None of the above

Text Solution

AI Generated Solution

The correct Answer is:
To determine the temperature coefficient of a reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definition**: The temperature coefficient of a reaction (often denoted as \( Q_{10} \)) is defined as the ratio of the rate constants of a reaction at two different temperatures, specifically when the temperature difference is 10 degrees Celsius. 2. **Identify the Formula**: The formula for the temperature coefficient can be expressed as: \[ Q_{10} = \frac{k_{T + 10}}{k_T} \] where \( k_{T + 10} \) is the rate constant at temperature \( T + 10 \) °C and \( k_T \) is the rate constant at temperature \( T \) °C. 3. **Choose the Temperature Range**: In this case, we typically consider a temperature range of 25 °C to 35 °C. Therefore, we can set: - \( T = 25 \) °C - \( T + 10 = 35 \) °C 4. **Apply the Formula**: Substitute the temperatures into the formula: \[ Q_{10} = \frac{k_{35}}{k_{25}} \] 5. **Interpret the Coefficient**: It is commonly observed that the rate of many reactions approximately doubles or triples with every 10 °C increase in temperature. This means: - If \( Q_{10} \approx 2 \), the reaction rate doubles. - If \( Q_{10} \approx 3 \), the reaction rate triples. 6. **Select the Correct Option**: Based on the information provided, the correct answer is likely found in option B, which discusses the ratio of the rate constants at 25 °C and 35 °C. ### Final Answer: The temperature coefficient of a reaction is defined as the ratio of the rate constants at two temperatures, specifically at a 10 °C difference. In this case, the correct option is B. ---
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