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The rate equation for the reaction CH3...

The rate equation for the reaction
`CH_3COOC_2H_5+H_2O to^([H^+]) CH_3COOH+C_2H_5OH` is: `(dx)/(dt)=k[CH_3 COOC_2H_5][H_2O]^0`
If the concentration of ester is doubled the rate becomes

A

Half

B

Twice

C

No change

D

Thrice

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given rate equation and determine how the rate of the reaction changes when the concentration of the ester is doubled. ### Step-by-Step Solution: 1. **Write the Given Rate Equation**: The rate equation for the reaction is given as: \[ \frac{dx}{dt} = k [CH_3COOC_2H_5][H_2O]^0 \] Here, \( k \) is the rate constant, \([CH_3COOC_2H_5]\) is the concentration of the ester, and \([H_2O]^0\) indicates that the concentration of water does not affect the rate (since any number raised to the power of 0 is 1). 2. **Understand the Impact of Doubling the Ester Concentration**: If the concentration of the ester \([CH_3COOC_2H_5]\) is doubled, we can denote the new concentration as: \[ [CH_3COOC_2H_5]_{new} = 2[CH_3COOC_2H_5] \] 3. **Substitute the New Concentration into the Rate Equation**: The new rate of the reaction, denoted as \( R_2 \), can be expressed as: \[ R_2 = k [CH_3COOC_2H_5]_{new} [H_2O]^0 \] Substituting the new concentration: \[ R_2 = k (2[CH_3COOC_2H_5]) [H_2O]^0 \] Since \([H_2O]^0\) is still equal to 1, we can simplify this to: \[ R_2 = 2k [CH_3COOC_2H_5] [H_2O]^0 \] 4. **Relate the New Rate to the Original Rate**: The original rate, denoted as \( R_1 \), is: \[ R_1 = k [CH_3COOC_2H_5] [H_2O]^0 \] Therefore, we can express \( R_2 \) in terms of \( R_1 \): \[ R_2 = 2R_1 \] 5. **Conclusion**: When the concentration of the ester is doubled, the rate of the reaction becomes: \[ R_2 = 2R_1 \] This means the rate of the reaction increases to twice its original value. ### Final Answer: The rate becomes **twice**. ---
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