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If two reactants part in a reaction, the...

If two reactants part in a reaction, then:

A

It can never be of second order

B

It can never be of first order

C

It can never be unimolecular

D

It can never be bimolecular

Text Solution

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The correct Answer is:
To solve the question "If two reactants part in a reaction, then:", we will analyze the implications of having two reactants in a chemical reaction in terms of reaction order and molecularity. ### Step-by-Step Solution: 1. **Understanding Reaction Order**: - The order of a reaction is determined by the sum of the powers of the concentration terms in the rate law expression. For a reaction involving two reactants A and B, if we assume it is an elementary reaction, the rate law can be expressed as: \[ \text{Rate} = k[A]^m[B]^n \] - Here, \(m\) and \(n\) are the stoichiometric coefficients of A and B, respectively. If both A and B participate in the reaction, their coefficients are typically 1 (assuming a simple reaction). 2. **Calculating Total Order**: - For the reaction \(A + B \rightarrow P\), the total order of the reaction would be: \[ \text{Total Order} = m + n = 1 + 1 = 2 \] - This indicates that the reaction is second order overall. 3. **Evaluating First Order**: - A reaction can be first order if the concentration of one reactant is significantly greater than the other, allowing it to be treated as a constant. For example, if [A] is much larger than [B], we can assume [A] remains constant, and the rate can be expressed as: \[ \text{Rate} = k' [B] \] - Here, \(k' = k[A]\) is a new constant. This means the reaction can exhibit first-order kinetics with respect to B. 4. **Molecularity Consideration**: - Molecularity refers to the number of reactant species involved in an elementary reaction. Since we have two reactants (A and B), the molecularity is bimolecular. - A reaction cannot be unimolecular if it involves two reactants because unimolecular reactions involve only one species undergoing a change. 5. **Conclusion**: - Therefore, if two reactants are participating in a reaction, it can be concluded that: - It can be of second order (as shown). - It can potentially exhibit first-order behavior under certain conditions. - It cannot be unimolecular because there are two reactants involved. ### Final Answer: If two reactants part in a reaction, then: - It can be of second order. - It can potentially exhibit first-order behavior under specific conditions. - It cannot be unimolecular.
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