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Reaction :2Br^- +H2O2+2H^+ to Br2+2H2O t...

Reaction :`2Br^- +H_2O_2+2H^+ to Br_2+2H_2O` takes place in two steps:
(a) `Br^- +H_2O_2 +H^+ to^(slow) HOBr+H_2O`
(b) `HOBr+Br^- +H^+ to^(fast) H_2O+Br_2`
The order of the reaction is

A

3

B

6

C

5

D

0

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction given by the steps: 1. **Identify the rate-determining step**: The first step of the reaction is labeled as slow, which indicates that it is the rate-determining step. This means that the rate of the overall reaction is governed by this step. 2. **Write the rate law for the rate-determining step**: The first step is: \[ \text{Br}^- + \text{H}_2\text{O}_2 + \text{H}^+ \rightarrow \text{HOBr} + \text{H}_2\text{O} \] The rate law can be expressed as: \[ \text{Rate} = k[\text{Br}^-][\text{H}_2\text{O}_2][\text{H}^+] \] Here, \(k\) is the rate constant, and the concentrations of the reactants are included. 3. **Determine the order of the reaction**: The order of the reaction is determined by the sum of the powers of the concentration terms in the rate law. In this case: - The power of \([\text{Br}^-]\) is 1. - The power of \([\text{H}_2\text{O}_2]\) is 1. - The power of \([\text{H}^+]\) is 1. Therefore, the overall order of the reaction is: \[ 1 + 1 + 1 = 3 \] 4. **Conclude the order of the reaction**: The order of the reaction is 3, which indicates that it is a third-order reaction. ### Final Answer: The order of the reaction is **3**. ---
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