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'Metals are usually not found as nitrate...

'Metals are usually not found as nitrates in their ores''. Out of the following two (`I`and `II`) reasons which is//are true for the above obervation?
`I`.Metal nitrates are highly unstable.
`II.` Metal nitrates are highly soluble in water.

A

`I` and `II` are true

B

`I` and `II` are false

C

`I` is false but `II` is true

D

`I` is true but `II` is false

Text Solution

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The correct Answer is:
C

Metals are usually not found as nitrates in their ores, because metal nitrates are highly soluble in water. For example, `KNO_3` (salt peter) would be classified as completely soluble. Thus, `KNO_3` could be expected to dissociate completely in aqueous solution to give `K^+` and `NO_3^-` ions.
`KNO_3 hArr K^(+)(aq) +NO_3^(-)(aq)`
The nitrate anion has three equivalent oxygen surrounding a central nitrogen atom. This tends to spread the single negative charge and make it easier for water (using hydrogen bonds) to separate the ions in solution.
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