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The major product obtained by the additi...

The major product obtained by the addition of HBr to 4-Methylpent-1-ene in the presence of an organic peroxide is

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`underset("1-Bromo-4-methlpentane")(CH_(3)-overset(CH_(3))overset(|)(C)HCH_(2)CH_(2)CH_(2)Br`
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The major product obtained by the addition reaction of HBr to 4-methylpent-1-ene in the presence of peroxide is:

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Find the products obtained by the addition of HBr "to hex -1-ene " (i) in the presence of preoxide (ii) in the absence of peroxide Also write their IUPAC names. (i) Strategy: In the presence of peroxides, the particle that attacks the double bond first is the large bromine atom. It attaches itself to the less hindered carbon atom to form a more stable free radical. The result is anti-Markovnikov's addition. (ii) Strategy: In the absence of peroxides, the particle that attacks the double bond first is a proton ( beacuse a proton is small, steric effect are not important). It attaches itself to a carbon atom by an ionic mechanism to form the most stable carbocation. The result is Markovnikov's addition.

The addition of HBr to but-1-ene in the presence of dibenzoyl peroxide yields

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Write IUPAC names of the products obtained by addition reactions of HBr to hex-1-ene (i) in the absence of peroxide and (ii) in the presence of peroxide.

DINESH PUBLICATION-HALOALKANES AND HALOARENES-Problem for practice
  1. Predict the major product in the following reactions (i). CH(3)-CH=C...

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  2. Name the reagents which can convert (a). 1-Chloropropane into 1-Nitr...

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  3. The major product obtained by the addition of HBr to 4-Methylpent-1-en...

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  4. Arrange the following compounds in correct decreasing order of reactiv...

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  5. From the given list, select the compound which can be converted into c...

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  6. Name the forces which influence the boiling points of alkyl halides.

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  7. Arrange the following compounds in order of ease of dehydrogenation by...

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  8. Identify the major product in the following reaction:

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  9. What is the correct order of decreasing nucleophilicity in non-polar s...

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  10. In the following pairs, which undergoes S(N^(2)) reaction more readily...

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  11. Name the product formed when benzene diazonium chloride is warmed with...

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  12. What is directional nature of halogen atom when attached to the benzen...

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  13. Out of chlorobenzene and chloroethane which is more readily hydrolysed...

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  14. What happens when bromobenzene is boiled with 50% NaOH solution?

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  15. Out of vinyl chloride and ethyl chloride which is more easily hydrolys...

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  16. Identify X, Y and Z in the following reaction (i). C(6)H(6)overset(C...

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  17. Out of benzyl chloride and chlorobenzene, which will give a white prec...

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  18. Arrange the following in decreasing order of reactivity towards aqueou...

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  19. Identify the product of the following reaction:

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  20. what is the correct order of the reactivity of the following compounds...

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