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Which of the following compounds (i) and...

Which of the following compounds (i) and (ii) will not react with a mixture of NaBr and `H_(2)SO_(4)`. Explain why ?
(i) `CH_(3)CH_(2)CH_(2)OH` (ii)

Text Solution

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NaBr reacts with `H_(2)SO_(4)` to evolves `Br_(2)` gas.
`2NaBr+3H_(2)SO_(4)to2NaHSO_(4)+SO_(2)+Br_(2)+2H_(2)O`
`Br_(2)` reacts with phenol in aqueous medium to form 2,4,6-dibromophenol.

`CH_(3)CH_(2)CH_(2)OH` does not react with bromine is not in a position to cleave `C-OH` bond in primary alcohol.
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