Home
Class 12
CHEMISTRY
Which of the following haloalkanes react...

Which of the following haloalkanes reacts with aqueous KOH most easily ? Explain giving reason.
(i). 1-Bromobutane
(ii) 2-Bromobutane
(iii) 2-Bromo-2-methylpropane
(iv). 2-Chlorobutane.

Text Solution

Verified by Experts

(iii) the compound is a tertiary alkyl halide. It reacts with aqueous KOH most easily. The reaction proceeds by `S_(N^(1))` mechanism. The tertiary carbocation formed in the slow or rate determining step is maximum stable.
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise Long Answer type Question|3 Videos
  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise Additional important questions|30 Videos
  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise NCERT|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    DINESH PUBLICATION|Exercise Brain Storming Multiple Chocie Questions|7 Videos
  • HYDROCARBONS

    DINESH PUBLICATION|Exercise All Questions|493 Videos

Similar Questions

Explore conceptually related problems

Classify the following compounds as primary, secondary and tertiary halides. (i) 1-bromobut-2-ene (ii). 4-Bromopent-2-ene (iii). 2-Bromo-2-methylpropane

Which compound in the following couples will react faster in S_(N^(2)) displacement reaction and why? (i). 1-Bromopentane or 2-Bromopentane (ii). 1-Bromo-2-methylbutane or 2-bromo-2-methyl butane.

Which of the following will react most easily with HCl in the presence of ZnCl_2 ?

Draw the bond line structures of the following compound whose IUPAC names are given as under : (a) 2-Bromobutane (b) 1-Chloro -3- Methylbutane (C) 2-Bromo-2-methylpropane , (d) 4-Chloro-4- methylpent -2- ene (e) 3-Iodo-3-methylpentane (f)2,3-Dibromobutane (g) 3-Iodopropene (h) Bromoethene (i) 1,4- Dibromobut -2-ene (j) 4-tert-Butyl-3-iodoheptane (k) 2-Chloro-3- metylpentane

Draw the bond line structures of the following compounds whose IUPAC names are given as under. (i) 2-Bromobutane (ii) 2- Bromo-2-methylpropane

DINESH PUBLICATION-HALOALKANES AND HALOARENES-Short Answer Type Questions
  1. Identify the product A and B formed in the following reaction: CH(3)...

    Text Solution

    |

  2. Which of the following compouds will have the highest melting point an...

    Text Solution

    |

  3. Write down the structures and IUPAC name for neo-pentylbromide.

    Text Solution

    |

  4. A hydrocarbon of molecular mass 72 g mol^(-1) gives a single monochlor...

    Text Solution

    |

  5. Name of the alkene which will yield/chloro 1-methylcyclohexane by its ...

    Text Solution

    |

  6. Which of the following haloalkanes reacts with aqueous KOH most easily...

    Text Solution

    |

  7. Why can aryl halides not be prepared by reaction of phenol with HCl in...

    Text Solution

    |

  8. which of the given compounds would undergo S(N^(1)) reaction faster an...

    Text Solution

    |

  9. Allyl chloride is hydrolysed more readily than n-propyl chloride. Why ...

    Text Solution

    |

  10. Why is it necessary to avoid even traces of moisture during the use of...

    Text Solution

    |

  11. How do polar solvents help in the first step in S(N)1 mechanism?

    Text Solution

    |

  12. Write a test to detect the presence of double bond in a molecule.

    Text Solution

    |

  13. Diphenyls are potential threat to the envioronment. How are these prod...

    Text Solution

    |

  14. What are the IUPAC names of the insecticide DDT and benzene hexachlori...

    Text Solution

    |

  15. Elimination reaction (especially beta - elimination) are as common as ...

    Text Solution

    |

  16. How will you obtain bromobenzene from aniline?

    Text Solution

    |

  17. Aryl halides are extremely less reactive towards nucleophilic substitu...

    Text Solution

    |

  18. Predict the major product formed when HCl is added to isobutylene. Exp...

    Text Solution

    |

  19. How can you obtain iodoethane from ethanol when no other iodine contai...

    Text Solution

    |

  20. Cyanide ion acts as an ambident nucleophille. From which end it acts a...

    Text Solution

    |