Home
Class 12
CHEMISTRY
Arrange the following compounds in incre...

Arrange the following compounds in increasing order of `S_(N^(1))` reactivity.
(a). (I). `ClCH_(2)CH=CHCH_(2)CH_(3)`, (II). `CH_(3)C(Cl)=CHCH_(2)CH_(3)`, (III). `CH_(3)CH=CHCH_(2)CH_(2)Cl`
(b). (I). `CH_(3)CH_(2)Br`, (II). `CH_(2)=CHCH(Br)CH_(3)`, (III). `CH_(2)=CHBr,`
(IV). `CH_(3)CH(Br)CH_(3)`
(c). (I). `(CH_(3))_(3)CBr`, (II). `(CH_(3))_(2)CHBr`, (III). `CH_(3)CH_(2)CH_(2)Br`,

Text Solution

Verified by Experts

The order of reactivyt of alkyl halies towards `S_(N^(1))` reactions is:
Allylic gt Tertiary gt Secondary gt primary gt Vinylic
Based on this, the increasing order of reactivity in different alkyl halides listed above is:
(a) (II) `lt(III)lt(I)`
(b). `(III)lt(I)lt(IV)lt(II)`
(c). `(III) lt (II) lt (I)`.
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise Question From board Examinations|72 Videos
  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise Higher Order Thinking Skills Questions|9 Videos
  • HALOALKANES AND HALOARENES

    DINESH PUBLICATION|Exercise Long Answer type Question|3 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    DINESH PUBLICATION|Exercise Brain Storming Multiple Chocie Questions|7 Videos
  • HYDROCARBONS

    DINESH PUBLICATION|Exercise All Questions|493 Videos

Similar Questions

Explore conceptually related problems

Arrange the folliwing compounds in increasing order of SN^(-2) reactivity. a. I.m ClCH_(2)CH = CHCH_(2)CH_(3) II. CH_(3)C(Cl) = CHCH_(2) CH_(3) III. CH_(3)CH = CHCH_(2)CH_(2)Cl IV. CH_(3)CH = CHCH_(2)(Cl) CH_(3) b. I. CH_(3)CH_(2)Br II. CH_(2) = CHCH(Br) CH_(3) III. CH_(2) = CHBr IV. CH_(3)CH (Br) CH_(3) C. I. (CH_(3))_(3)CCl , II. C_(6)H_(5)C(CH_(3))_(2)Cl III. (CH_(3))_(2)CHCl , IV. CH_(3)CH_(2)CH_(2)Cl

Arrange the following halides in the decreasing order of SN^1 reactivity : (I) CH_3CH_2CH_2Cl, (II) CH_2=CHCH(Cl)CH_3 (III) CH_3CH_2CH(Cl)CH_3

Arrange the following halides in the decreasing order of S_(N^(1)) reactivity : underset((I))(CH_(3)CH_(2)CH_(2)Cl), underset((II)) (CH_(2)=CHCH(Cl)CH_(3)), underset((III))(CH_(3)CH_(2)CH(Cl)CH_(3))

Arrange the following compounds in decreasing order of their boiling points (i) CH_(3)Cl (ii) CH_(3)CH_(2)Cl (iii) CH_(3)CH_(2)CH_(2)Cl (iv) CH_(3)CH_(2)CH_(2)CH_(2)Cl

Arrange the following in increasing order of their expected S_(N)1 reactivity : (i) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)Br, CH_(2)=CHBr, CH_(2)=CHCH(Br)CH_(3) (ii) ClCH_(2)CH=CHCH_(2)CH_(3), CH_(3)C(Cl)=CHCH_(2)CH_(3), CH_(3)CH=CHCH_(2)CH_(2)Cl, CH_(3)CH=CHCH(Cl)CH_(3) (iii) (CH_(3))_(3)C Cl, C_(6)H_(5)C(CH_(3))_(2)Cl,(CH_(3))_(2)CHCl, CH_(3)CH_(2)CH_(2)Cl

Arrange the following in increasing order of acid strength : (i) CH_(3)CH_(2)CH(Br)COOH , (ii) CH_(3)CH(Br)CH_(2)COOH , (iii) CH_(3)COOH

DINESH PUBLICATION-HALOALKANES AND HALOARENES-Additional important questions
  1. Which compound in the following pairs would react faster in S(N^(2)) d...

    Text Solution

    |

  2. Arrange the following compounds in increasing order of their densities...

    Text Solution

    |

  3. predict the product of the following reaction underset(CH(3)-underse...

    Text Solution

    |

  4. Which product is formed when trans-2-phenyl-1-bromocyclopentane is tre...

    Text Solution

    |

  5. Alkyl chlorides can be prepared by refluxing alcohol with thionyl chlo...

    Text Solution

    |

  6. Why is chlopropyl chloride less reactive than cyclopentyl chloride tow...

    Text Solution

    |

  7. When heated to 300^(@)C neopentyl chloride forms 2-chloro-2-methylbuta...

    Text Solution

    |

  8. Perfluorocarbons are remarkable stable, why?

    Text Solution

    |

  9. Identify the compound in the following pair that reacts with sodium io...

    Text Solution

    |

  10. Give the major products when 2-Bromo 3-methylbutane is reacted with so...

    Text Solution

    |

  11. Two alkyl halides A and B with molecular formula C(7)H(15)Cl have diff...

    Text Solution

    |

  12. Why does not ammo0nolysis of alkyl halides yield pure amines?

    Text Solution

    |

  13. 2-Bromopentane is treated with alcoholic KOH solution. What is the maj...

    Text Solution

    |

  14. Explain why displacement of cyanide ion and amide ion by other nucleop...

    Text Solution

    |

  15. Why is chloroform not used as anaesthetic these days? What is the comm...

    Text Solution

    |

  16. Explain the formation of the products in the following reaction. CH(...

    Text Solution

    |

  17. Arrange the following compounds in increasing order of S(N^(1)) reacti...

    Text Solution

    |

  18. Explain why reaction of HCl with CF(2)CH=CH(2) proceeds according to a...

    Text Solution

    |

  19. Predict the order of reactivity of following compound in S(N^(1)) reac...

    Text Solution

    |

  20. Out of CH(3)overset(o+)(C)HCH(3) and CF(3)overset(o+)(C)HCH(3) which i...

    Text Solution

    |