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In alkaline hydrolysis of a tertiary hal...

In alkaline hydrolysis of a tertiary halide by aqueous alkali, if concentration of alkali is doubled, then the reaction rate

A

will be doubled.

B

will be halved

C

will become four times greater

D

will remain constant.

Text Solution

Verified by Experts

The correct Answer is:
D

In tertiary alkyl halides, the reaction rate depends upon the concentration of tertiary alkyl halide only sinice it proceeds by `S_(N^(1))` mechanism. Since the concentration of alkyl halide does not change, reaction rate remains unchanged.
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DINESH PUBLICATION-HALOALKANES AND HALOARENES-Multiple choice
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  2. For the following reactions: (A). CH(3)CH(2)CH(2)Br+KOHoverset((alc))t...

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  3. The correct order of the reactivity of the following compounds towards...

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  4. consider the reaction CH(3)CH(2)CH(2)Br+NaCNtoCH(3)CH(2)CH(2)CN+NaBr...

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  5. Which of the following can be used as halide component for Friedel-Cra...

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  6. Bromination of trans but-2-ene leads to the formation of

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  7. The compound C(7)H(8) undergoes the following reaction. C(7)H(8)over...

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  8. The decreasing order of S(N^(2)) reaction for the given compounds is .

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  9. The correct order of reactivity in S(N^(1)) reaction for the following...

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  10. An alkyl bromide produces a single alkene when it reacts with sodium e...

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  11. CH(3)-underset(CH(3))underset(|)(CH)-CH=CH(2)+HBr to 'A' 'A' (predom...

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  12. In a set of reaction, ethyl benzene yielded a product D. The prod...

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  13. In alkaline hydrolysis of a tertiary halide by aqueous alkali, if conc...

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  14. An alkyl halide with molcular formula C(6)H(13)Br on dehydrohalogenati...

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  15. Which one of the following is most reactive towards nucleophilic subst...

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  16. The major product (A) of the following reactions is:

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  17. The products expected to be formed in the wurtz reaction of a mixture ...

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  18. The major organic products in the given reaction. .

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  19. Which one of the following does not show optical activity ?

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  20. Identify A and predict the type of reaction.

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