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For the following compounds, the correct...

For the following compounds, the correct statement(s) with respect to nucleophilic substitution reaction is(are)

A

Compound IV undergoes inversion of configuration

B

The order of reactivity for I, III and IV is:
IVgtIgtIII

C

I and III follows `S_(N^(1))` mechanism

D

I and II follows `S_(N^(2))` mechanism

Text Solution

Verified by Experts

The correct Answer is:
A, C, D


Option (a) is correct as compound (iv) undergoes inversion of configuration.
Option (c) is correct because both (I) and (III) can follows `S_(N^(2))` mechanism provided the medium is highly polar as well as protic.
(d). Option (d) is also correct because both I & II can follows `S_(N^(2))` mechanism provided provided the medium is polar aprotic and nucleophile is strong.
(b). Option (b) is not correct because the order of reactivity is not correct for `S_(N^(1))` and `S_(N^(2))` mechanisms.
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DINESH PUBLICATION-HALOALKANES AND HALOARENES-Straight Objective type
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  4. Among the following molecules the one with highest dipole moment is:

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  5. The reagent for the above conversion is:

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  6. The major product of the following reaction is:

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  7. The synthesis of compound 3-octyne is achieved by adding a bromoalkane...

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  8. KI dissolved in acetone undergoes S(N^(2)) reaction with each of P,Q,R...

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  9. Aryl halids are less reactive rtowards nucleophilic substitution react...

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  10. The compound used as refrigerant are:

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  11. Reagent which cannot be used to distinguish allyl bromide from n-propy...

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  12. Benzyl chloride (C(6)H(5)CH(2)Cl) can be prepared from toluene by chlo...

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  13. The correct statement(s) about the compound given below is (are):

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  14. Which of the given statement(s) about N,O,P and Q with respect to M is...

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  15. Compound(s) that on hydrogenation produce(s) optically inactive compou...

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  16. Choose the correct statement(s) among the following:

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  17. Among the following reaction(s) which gives (give) tert-butyl benzene ...

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  18. The IUPAC naem(s) of the following compound is (are):

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  19. The correct statement(s) for the following addition reactions is (are)...

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  20. For the following compounds, the correct statement(s) with respect to ...

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