Home
Class 12
CHEMISTRY
For 10^(-4) M BOH (weak base) ,K(b)=5xx...

For `10^(-4)` M BOH (weak base) ,`K_(b)=5xx10^(-5))`:

A

`alpha=0.707`

B

`[OH^(-)]=5xx10^(-5)M`

C

`pH=9.85`

D

All of these

Text Solution

Verified by Experts

`alpha=sqrt((5xx10^(-5))/(10^(-4)))gt0.1` So `(Calpha^(2))/(1-alpha)=K_(b)rArr 5xx10^(-5)=(10^(-4)alpha^(2))/(1-alpha)rArr 2alpha^(2)+alpha-1=0rArr alpha=0.5`
Hence `[OH^(-)]=Calpha=5xx10^(-5)&pH=9.7`
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    RESONANCE|Exercise Exercise 2 part I only one correct type|10 Videos
  • IONIC EQUILIBRIUM

    RESONANCE|Exercise Part -II Single and double value integer type|8 Videos
  • IONIC EQUILIBRIUM

    RESONANCE|Exercise Exercise -1|17 Videos
  • HYDROCARBON

    RESONANCE|Exercise ORGANIC CHEMISTRY(Hydrocarbon)|50 Videos
  • IUPAC NOMENCLATURE & STRUCTURAL ISOMERISM

    RESONANCE|Exercise Advanced Level Problems Part-5|2 Videos

Similar Questions

Explore conceptually related problems

Calculate the hydrolysis constant of a salt of week acid (K_(a) = 2 xx 10^(-6)) and of a weak base (K_(b) = 5 xx 10^(-7))

HA is a weak acid [K_(a) = 10^(-4)] and BOH is a weak base [K_(b) = 10^(-5)] . BA is the salt formed from them, In the aquoeus solution of BA

NH_(4)CN is a salt of weak acid HCN(K_(a)=6.2xx10^(-10)) and a weak base NH_(4)OH(K_(b)=1.8xx10^(-5)) . 1 molar solution of NH_(4)CN will be :-

HCN is a weak acid (K_a=6.2xx10^(-10)).NH_4 OH is a weak base (K_b=1.8xx10^(-5)). A 1 M solution of NH_4CN would be

NH_(4)CN is a salt of weak acid HCN (Ka=6.2xx10^(-10)) and a weak base NH_(4)OH(K^(b)=1.8xx10^(-5)) A one molar solution of NH_(4)CN will be :-

NH_4F is a salt of weak acid HF ( ka = 7.2 xx 10^(-4)) and weak base NH_4OH ( kb = 1.8 xx 10^(-5)) , the solution of NH4F will be

Calculate pOH of 0.1 M aq. Solution of weak base BOH (K_(b)=10^(-7)) at 25^(@)C.

For a solution obtained by mixing equal volumes of 0.02M KOH solution &0.2MB (weak diacidic base), K_(b_(1))=10^(-7) & K_(b_(2))=10^(-14)) solution:

RESONANCE-IONIC EQUILIBRIUM-Part -II (only one option correct type)
  1. K(a) for formic acid and acetic acid are 2.1xx10^(-4) and 1.1xx10^(-5)...

    Text Solution

    |

  2. K(a) for monobasic acid ,whose 0.1M solution has pH of 4.5 is :

    Text Solution

    |

  3. For 10^(-4) M BOH (weak base) ,K(b)=5xx10^(-5)):

    Text Solution

    |

  4. For, H(3)PO(4)+H(2)OhArrH(3)O^(+)+H(2)PO(4)^(-), K(a(1)) H(2)PO(4)+H...

    Text Solution

    |

  5. In a 0.2M aqueous solution of Ethylene diamine (H(2)NCH(2)CH(2)NH(2)):...

    Text Solution

    |

  6. The dissociation constant of acetic acid at a given temperature is 1.6...

    Text Solution

    |

  7. In above question concentration of Triethyl ammonium ion [C(6)NH(16)]^...

    Text Solution

    |

  8. Consider an aqueous solution 0.1 M each in HOCN, HCOOH, (COOH)2 and H3...

    Text Solution

    |

  9. What are [H^(o+)], [A^(Theta), and [B^(Theta)] in a solution that is 0...

    Text Solution

    |

  10. pH of solution obtained by mixing equal volumes of 0.1M Triethyl amine...

    Text Solution

    |

  11. In a solution containing 0.1M HCl & 0.1M H(3)PO(4) (having dissociatio...

    Text Solution

    |

  12. For a solution obtained by mixing equal volumes of 0.02M KOH solution ...

    Text Solution

    |

  13. A pair of salts are given in a solution each is 0.1 M in concentration...

    Text Solution

    |

  14. Aqueous solution of NH(4)Cl is …… in nature due to behaviour of….ion i...

    Text Solution

    |

  15. The pH of a solution obtained by mixing 100mL of 0.3M CH(3)COOH with ...

    Text Solution

    |

  16. The sodium salt of a certain weak monobasic organic acid is hydrolysed...

    Text Solution

    |

  17. The pH of 0.1M solution of the following salts decreases in the order

    Text Solution

    |

  18. The degree of hydrrolysis of a salt of weak acid and weak base in its ...

    Text Solution

    |

  19. Select the correct statement regarding above solution.

    Text Solution

    |

  20. pH of 0.1M Na(2)HPO(4) and 0.2M NaH(2)PO(4) are respectively: (pK(a)"f...

    Text Solution

    |