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B+underset(conc.)(HNO(3))tounderset("whi...

`B+underset(conc.)(HNO_(3))tounderset("white solid")(A)+underset("brown gas")(B)`
How many of the following statements are correct regarding products (A) & (B) ?
(1) `(A)` can be prepared by reacting borax with dilute acids.
(2) `(A)` is a weak monobasic lewis acid.
(3) `(A)` behaves like an electrolyte when dissolved in water.
(4) `(A)` can be prepared by reacting colemanite, `SO_(2)` & `H_(2)O`
(5) `(B)` is paramagnetic in nature.
(6) `(B)` is a mixed anhydride.
(7) `(B)` does not forms a dimer
(8) `(B)` reacts with `NaOH(aq)` undergoing disproportionation.
(9) Bond angle about central atom is greater in `(A)` than in `(B)`. (Assume atom forming maximum number of bonds as central atom)

Text Solution

Verified by Experts

`2B+6HNO_(3)("conc")to underset((A))(2H_(3)BO_(3))+underset((B))(6NO_(2))`
`NO_(2)` forms a dimer `N_(2)O_(4)` (diamagnetic white solid)
Bond angle about Boron in `H_(3)BO_(3)(=120^(@))` is less than bond angle about `N` in `NO_(2)(132^(@))`
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RESONANCE-P-BLOCK ELEMENT (BORON AND CARBON FAMILY)-Exercise-2 Part-II : SINGLE AND DOUBLE VALUE INTEGER TYPE
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  4. How many of the following order of bond energies are correct. (i) C...

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  5. Which of the following Salts are amphoteric in anture. PbO,PbO(2), ...

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  8. 4 moles of NaBH(4) react completely with I(2). calculate volume of ...

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  9. The number of oxygen atoms in borax which do not from ppi-ppi back bon...

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  10. How many compounds show amphoteric nature amongst following B(2)O(3)...

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  11. How many compounds form acidic solution when dissolved in water H(3)...

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