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The correct statement (s) for orthoboric...

The correct statement (s) for orthoboric acid is/are

A

It behaves as a weak acid in water due to self ionization.

B

Acidity of its aqueous solution increases upon addition of ethylene glycol.

C

It has a three dimensional structure due to hydrogen bonding.

D

It is weak electrolyte in water.

Text Solution

Verified by Experts

The correct Answer is:
B, D

`H_(3)BO_(3)` does not undergo self ionization.
On adding cis-diols, them form complexing species with orthoboric acid.
Hence the acidity increase on adding ethylene glycol.
`H_(3)BO_(3)+H_(2)OtoB(OH)_(4)^(-)+H^(+)`

It arranges into planar sheets due to `H`-bonding.
Hence, it has `2`-dimensional structure due to `H` bonding.
It acts as a weak acid in water, so it is a weak electrolyte in water
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