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Why Zn(II) salt is not precipitated as Z...

Why `Zn(II)` salt is not precipitated as `Zn(OH)_(2)` by ammonia solution in the presence of excess of ammonium

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`Zn^(2+)+2 NH_(3)+2H_(2)OhArrZn(OH)_(2)darr+2NH_(4)^(+)`
It is due to the lowering of `OH^(-)` ion concentration because of common ion effect of `NH_(4)^(+)` to such a value that the `K_(sp)` of `Zn(OH)_(2)` is not attained.
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Statement-1: Zinc ions are not precipitated by ammonia solution as zinc hydroxide, in the presence of ammonium chloride. Statement-2: Presence of ammonium chloride lowers the hydroxy-ion concentration to such a value that the solubility product of Zn(OH)_(2) is not attained.

White precipitate of Zn(OH)_(2) dissolves in:

Zn(OH)_(2)darr is soluble in:

Partial precipitation of Mn^(2+) as Mn(OH)_(2) occurs with ammonia solution but the precipitate is soluble in ammonium salts. Explain?

Which of the following statements is // are correct ? (I) White precipitate of Zn(OH)_(2) is soluble in excess ammonia and in solutions of ammonium salts. (II) Yellow precipitate of barium chromate is soluble in dilute acetic acid as well as in mineral acids. (III) Green precipitate of Ni(OH)_(2) is soluble in excess sodium hydroxide.

Zn(OH)_(2) is not precipitated when NH_(4)OH is added to a zinc salt solution containing some ammonium chloride. Explain.

Magnesium is not precipitated from a solution of its salt by NH_(4)OH in the presence of NH_(4)CI. Explain.

RESONANCE-QUALITATIVE ANALYSIS PART 1-EXERCISE 1 PART 2 QUALITATIVE ANALYSIS
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  2. What products are formed when precipitate formed by the reaction of Hg...

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  3. Why do lead salts turn black on keeping for a long time in the laborat...

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  4. Name one chloride which is soluble in hot water as well as in excess o...

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  5. Does mercuric sulphide dissolve in sodium sulphide solution (of 2M)?

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  6. What happens when white precipitate of Bi(OH)(3) is boiled ?

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  7. Why Na(2)S cannot be used in place of H(2)S (in presence of HCl) as a ...

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  8. Is their any reaction other then cyanide reaction which can be used fo...

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  9. Which basic radical is tested with the help of alkaline sodium stannit...

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  10. What happens when ammonium sulphide solution reacts with a solution co...

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  11. Can Cr(III) salt be oxidised to Cr(VI) salt by potassium (or ammonium)...

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  12. Do Fe(III) salts and Fe(II) salts both give red colouration with dimet...

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  13. Which colour precipitate is fomed by Fe(II) salt with potassium ferroc...

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  14. Which basic radical(s) decolourize acidic KMnO(4) ?

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  15. Partial precipitation of Mn^(2+) as Mn(OH)(2) occurs with ammonia solu...

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  16. What happens when Mn(II) ions free from chloride ions react with acidi...

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  17. Why Zn(II) salt is not precipitated as Zn(OH)(2) by ammonia solution i...

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  18. What will happen if the precipitation of V^(th) group cation by ammoni...

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  19. What happens when ammonium sulphate solution is added to a solution c...

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  20. Which colour precipitate is obtained when a solution of Ca^(2+) ions r...

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