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Na(2)SO(4) and Na(2)S can be distinguish...

`Na_(2)SO_(4)` and `Na_(2)S` can be distinguished from each other by using:

A

dilute `H_(2)SO_(4)`

B

acidified `KMnO_(4)` solution

C

sodium nitroprusside solution

D

cadmium acetate solution

Text Solution

Verified by Experts

The correct Answer is:
A,B,C,D

(A)`Na_(2)S+H^(+)toH_(2)Suarr+2Na^(+).,Na_(2)SO_(4)` gives no reaction with `H_(2)SO_(4)`
(B)`2MnO_(4)^(-)`(pink solution)+`5H_(2)S+6H^(+) to 2Mn^(2+)` (colourless) +`5S darr +8H_(2)O`
No colour change is observed with `Na_(2)SO_(4)`
( C)`S^(2-)+[Fe(CN)_(5)NO]^(2-) to [Fe(CN)_(5)NOS]^(4-)` (purple or violet colouration)
No colour change is observed with `Na_(2)SO_(4)`
(D)`S^(2-)+Cd^(2+) to CdS darr` (yellow).
`Na_(2)SO_(4)` forms `CdSO_(4)` which is water soluble.
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