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Passing H(2)S gas into a mixture of Mn^(...

Passing `H_(2)S` gas into a mixture of `Mn^(2+) , Ni^(2+) , Cu^(2+)` and `Hg^(2+)` ions in an acidified aqueous solution precipitatates:

A

`CuS` and `HgS`

B

`MnS` and `NiS`

C

`MnS` and `NiS`

D

`NiS` and `HgS`

Text Solution

Verified by Experts

The correct Answer is:
A

In presence of acidic medium, ionisation of `H_(2)S` is supressed to less number of `S^(2-)` ions are produces.So only those sulphides are precipitated which have low solubility product `(K_(sp))` value, For example `CuS` and `HgS`.
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