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Which of the following statements are co...

Which of the following statements are correct?

A

The C-Cl bond in chlorobenzene is shorter than in chloromethane.

B

The C-Cl bond in chlorobenzene has some double bond character.

C

It is difficult to replace chlorine from chlorobenzene than from bernzyl chloride.

D

Chlorobenzene on further chlorination gives m-dichlorobenene.

Text Solution

AI Generated Solution

To determine which statements are correct regarding the properties of alkyl and aryl halides, let's analyze each statement step by step. ### Step 1: Analyzing the First Statement **Statement:** The C-Cl bond in chlorobenzene is stronger than in chloromethane. - **Explanation:** In chlorobenzene (C6H5Cl), the chlorine atom is bonded to a carbon in a benzene ring. The presence of the aromatic system allows for resonance stabilization, which means that the C-Cl bond is somewhat strengthened due to the delocalization of electrons. In chloromethane (CH3Cl), the C-Cl bond does not benefit from such resonance, making it weaker. Therefore, this statement is **correct**. ### Step 2: Analyzing the Second Statement ...
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FIITJEE-ALKYL AND ARYL HALIDES-SOLVED PROBLEMS [OBJECTIVE]
  1. In the above case

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  3. Arrange the following compounds in the order of leaving group ability

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  4. Which of the following has the highest nucleophilicity ?

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  5. An SN^2 reaction of an asymmetric carbon of a compound always gives :

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  6. A solution of (+)-2-chloro-2-phenyl ethane in toluene racemises slowly...

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  7. o-Chlorotoluene reacts with sodamide in liquid NH(3) to give o-toluidi...

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  8. Which of the following will give yellow precipitate with l(2)//NaOH?

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  9. Which of the following derivatives of benzene would undergo hydrolysis...

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  10. Which of the following nucleophilie has highest S(N)^(2) reactivity?

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  11. Which of the following on treatment with NaNH(2) in liquid NH(3) gives...

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  12. For the above reaction the corresponding intermediates are

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  13. C(2)underset((A))(H(4))Cl(2)overset(KCN)to(B)overset(H(2)O^(+))to(C)ov...

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  14. Which of the following compounds will give haloform test?

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  15. Dipole moment is shown by

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  16. Which of the following statements are correct?

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  17. Grignard reagents (RMgX) are prepared by the reaction of an organic ha...

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  18. Grignard reagents (RMgX) are prepared by the reaction of an organic ha...

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  19. Grignard reagents (RMgX) are prepared by the reaction of an organic ha...

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  20. Grignard reagents (RMgX) are prepared by the reaction of an organic ha...

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