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Which of the following compounds will gi...

Which of the following compounds will give `S_(N)1` reaction in polar protic solvent:

A

`H_(3)C-overset(Br)overset(|)CH-C_(6)H_(5)`

B

`H_(3)C-underset(CH_(3))underset(|)overset(Cl)overset(|)C-CH_(2)-Cl`

C

`H_(2)C=CH-overset(Br)overset(|)CH-CH_(3)`

D

All of the above

Text Solution

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The correct Answer is:
D
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Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consits of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. Which one of the following compound will give S_(N)1 reaction predominantly?

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FIITJEE-ALKYL AND ARYL HALIDES-ASSIGNMNET PROBLEMS [OBJECTIVE] <br> LEVEL-I
  1. Predict the compound which will undergo solvolysis (aqueous ethanol) m...

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  2. Which of the following compounds will be most reactive for S(N)1 react...

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  3. Which of the following compounds will give S(N)1 reaction in polar pro...

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  4. Which of the following combinations is correctly matched?

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  5. In the reaction H(3)C-overset(Br)overset(|)CH-CH(2)-Brunderset((ii)C...

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  6. Two isomeric halo alkenes (A) and (B) have molecular formula C(5)H(9)C...

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  7. A chloro derivative (X) on treatment with Zn and HCl gave a hydrocarb...

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  8. An alkyl halide of formula C(6)CH(13)Cl on treatment with potassium t-...

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  9. 2,2-Dechloro-3-methyl butane on hydrolysis forms

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  10. 1- Chlorobutane on reaction with alchloic potash gives:

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  11. The product obtained by reduction of benzyl bromide with LIAIH(4...

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  12. 3-Methyl-2-pentene on reaction with HOCl gives-

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  13. When ethyl alcohol and KI reacted in presence of Na(a)CO(3) yellow cry...

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  14. An organic compound X(C(4)H(9)Br) on treatment with alc, KOH gave isom...

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  15. n-Butane reacts with Br(2) at 130^(@) to give more amount of

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  16. Chloroform easily gets converted to poisonous phosgene in the presence...

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  17. In CH(3)-CH(2)-CH(2)-Br,C-Br bond is formed by the overlapping of

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  18. beta-Phenyl ethyl chloride is the minor product obtained by reaction o...

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  19. Which of the following will react fastest with Ag^(+) ?

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  20. Which of the following compound will react with aq. NaOH?

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