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2,2-Dechloro-3-methyl butane on hydrolys...

2,2-Dechloro-3-methyl butane on hydrolysis forms

A

Diethyl ketone

B

methyl isopropyl ketone

C

3-methyl butance 2,3 diol

D

2-methyl butane 2,3 doil

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The correct Answer is:
To solve the problem of what 2,2-Dichloro-3-methylbutane forms upon hydrolysis, we can follow these steps: ### Step 1: Understand the Structure 2,2-Dichloro-3-methylbutane has the following structure: - The butane chain has a total of four carbon atoms. - There are two chlorine atoms attached to the second carbon (C-2). - There is a methyl group attached to the third carbon (C-3). ### Step 2: Hydrolysis Reaction When 2,2-Dichloro-3-methylbutane undergoes hydrolysis, it reacts with water (or an alcohol) to replace the chlorine atoms with hydroxyl (OH) groups. ### Step 3: Formation of Carbocation The hydrolysis begins with the formation of a carbocation. The chlorine atoms are good leaving groups, and when one of them leaves, it generates a secondary carbocation at the C-2 position. This carbocation is stabilized by the inductive effect of the neighboring carbon atoms. ### Step 4: Nucleophilic Attack Water (acting as a nucleophile) attacks the carbocation. The oxygen in water has a partial negative charge and will bond with the positively charged carbon atom (C-2). This results in the formation of an intermediate where the OH group is attached to C-2. ### Step 5: Deprotonation The intermediate formed has a positively charged hydroxyl group (OH2+). A proton (H+) is removed from this intermediate, resulting in the formation of a neutral alcohol. ### Step 6: Final Product The final product of this hydrolysis reaction is 2,3-Dimethylbutan-2-ol, which can also be referred to as 2,3-diol due to the presence of two hydroxyl groups on the second and third carbons. ### Conclusion Thus, the hydrolysis of 2,2-Dichloro-3-methylbutane yields **2,3-Dimethylbutan-2-ol**. ---
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FIITJEE-ALKYL AND ARYL HALIDES-ASSIGNMNET PROBLEMS [OBJECTIVE] <br> LEVEL-I
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  11. In CH(3)-CH(2)-CH(2)-Br,C-Br bond is formed by the overlapping of

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  13. Which of the following will react fastest with Ag^(+) ?

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  14. Which of the following compound will react with aq. NaOH?

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  15. Identify (Z) in the following reaction serices: CH(3)CH(2)CH(2)Brove...

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