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Suggest the mechanism when benzene is tr...

Suggest the mechanism when benzene is treated with ethylene chloride in presence of `AlCl_(3)`.

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What happens when : (i) Propene is treated with HBr in presence of peroxide. (ii) Benzene is treated with methyl chloride in presence of AlCl_(3)

Benzene is treated with isobutyl alcohol in presence of conc. H_(2)SO_(4)

Knowledge Check

  • What happens when aniline is treated with methyl chloride in presence of AlCl_(3) ?

    A
    It undergoes Friedel Craft reaction to form a mixture of p- methyl and o - methylaniline
    B
    It does not undergo Friedel Craft reaction because `AlCl_(3)` reacts with aniline instead of reacting with alkyl halide
    C
    Aniline gets positive charge and deactivated for electrophilic substitution
    D
    Both (b) and (c )

  • Benzene reacts with acetyl chloride in the prescence of anhydrous AlCl_(3) to give

    A
    phenyl acetate
    B
    benzoyl chloride
    C
    chlorobenzene
    D
    acetophenone

  • Nitrobenzene reacts with acetyl chloride in the presence of anhydrous AlCl_(3) to from

    A
    `2-` nitrogacetophenone
    B
    `3-`nitroacetophenone
    C
    `4-`nitroacetophenone
    D
    none of these

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    Benzene is treated with isobutyl alcohol in presence of conc. H_(2)SO_(4)

    Name the final product of the following reactions : (i) Benzene is treated with methyl chloride in presence of anhydrous aluminium chloride. (ii) Benzene is treated with acetyl chloride in the presence of anhydrous aluminium chloride. (iii) Phenol is heated with zinc. (iv) Sodium benzoate is heated with soda lime. (v) Benzene is treated with fumining nitric acid in presence of conc. H_(2)SO_(4) . (vi) Benzene is catalytically hydrogenated. (vii) Ozone reacts with benzene. (viii) Toluene is treated with a mixture of conc. CNO_(3) and conc. H_(2)SO_(4) . (ix) Chlorine is passed through boiling toluene. (x) Toluene is heated with acidic potassium premanganate solution. (xi) Toluene in carbon tetrachloride is oxidised by chromyl chloride. (xii) Ortho-xylene is oxidised with hot acidic K_(2)Cr_(2)O_(7) solution.

    Predict product formed when benzene is treated with iodine chloride in presence of anhydrous aluminium chloride.

    Ethylbenzene can be prepared from benzene by Friedel- Crafts reaction in the following manner. (i) by treating with ethyl chloride in presence of AICI_(3) (ii) by treating excess of benzene with ethyl chloride in presence of AICI_(3) (iii) by treating benzene with vinyl chloride in presence of AICI_(3) followed by reduction (iv) by acetylation of benzene followed by Clemmerisen reduction

    Which reaction is fastest with benzene in presence of AlCl_3?

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