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If a compound is AB4 is polar then its s...

If a compound is `AB_4` is polar then its strcture is similar to

A

Square planar

B

Tetrahedral

C

Trigonal bipyramidal

D

Rectangular planar

Text Solution

AI Generated Solution

The correct Answer is:
To determine the structure of a polar compound represented by the formula \( AB_4 \), we need to analyze the molecular geometry and the resulting dipole moments. Here’s a step-by-step solution: ### Step 1: Understand the Structure of \( AB_4 \) The compound \( AB_4 \) consists of one central atom \( A \) and four surrounding atoms \( B \). The arrangement of these atoms can lead to different molecular geometries. **Hint:** Consider common geometries for compounds with four surrounding atoms, such as tetrahedral, square planar, and trigonal bipyramidal. ### Step 2: Analyze Possible Geometries 1. **Tetrahedral Geometry**: In a tetrahedral arrangement, all four \( B \) atoms are symmetrically placed around the \( A \) atom. If \( B \) is more electronegative than \( A \), the dipole moments from each \( A-B \) bond will cancel out due to symmetry, resulting in a non-polar molecule. **Hint:** Visualize the tetrahedral shape and the direction of dipole moments. 2. **Square Planar Geometry**: In a square planar arrangement, the \( B \) atoms are positioned at the corners of a square with \( A \) at the center. Similar to the tetrahedral case, the dipole moments will cancel each other out, leading to a non-polar molecule. **Hint:** Draw the square planar structure and observe the symmetry. 3. **Trigonal Bipyramidal Geometry**: In this geometry, three \( B \) atoms occupy the equatorial plane while one \( B \) atom is above and one below the plane. If there is a lone pair on \( A \), the dipole moments will not cancel out, resulting in a net dipole moment and thus a polar molecule. **Hint:** Consider how lone pairs affect the molecular geometry and dipole moments. ### Step 3: Conclusion Based on the analysis, the only geometry that can lead to a polar molecule is the **trigonal bipyramidal** structure with a lone pair on the central atom \( A \). Therefore, the structure of a polar compound \( AB_4 \) is similar to a trigonal bipyramidal arrangement with one lone pair. **Final Answer:** The structure of a polar compound \( AB_4 \) is similar to a **trigonal bipyramidal** structure with a lone pair.
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