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For lyman series lambdamax -lambdamin = ...

For lyman series `lambda_max` -`lambda_min` = `340 Angstrom` . Find same for paschen series

A

11,802 Angstroms

B

13,802 Angstroms

C

12,502 Angstroms

D

10,000 Angstroms

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The correct Answer is:
To solve the problem of finding the difference between the maximum and minimum wavelengths for the Paschen series, we will follow these steps: ### Step-by-Step Solution: 1. **Understanding the Series**: - The Lyman series corresponds to transitions where the electron falls to the n=1 energy level. - The Paschen series corresponds to transitions where the electron falls to the n=3 energy level. 2. **Identifying Maximum and Minimum Wavelengths**: - For the Lyman series: - **Maximum Wavelength (λ_max)**: This occurs for the transition from n=2 to n=1. - **Minimum Wavelength (λ_min)**: This occurs for the transition from n=∞ to n=1. - For the Paschen series: - **Maximum Wavelength (λ_max)**: This occurs for the transition from n=4 to n=3. - **Minimum Wavelength (λ_min)**: This occurs for the transition from n=∞ to n=3. 3. **Using the Rydberg Formula**: The Rydberg formula for the wavelength of emitted light is given by: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant. 4. **Calculating λ_min for Paschen Series**: - For λ_min in the Paschen series (n1=3, n2=∞): \[ \frac{1}{\lambda_{\text{min}}} = R \left( \frac{1}{3^2} - 0 \right) = \frac{R}{9} \] Therefore, \[ \lambda_{\text{min}} = \frac{9}{R} \] 5. **Calculating λ_max for Paschen Series**: - For λ_max in the Paschen series (n1=3, n2=4): \[ \frac{1}{\lambda_{\text{max}}} = R \left( \frac{1}{3^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{9} - \frac{1}{16} \right) \] To simplify: \[ \frac{1}{\lambda_{\text{max}}} = R \left( \frac{16 - 9}{144} \right) = \frac{7R}{144} \] Therefore, \[ \lambda_{\text{max}} = \frac{144}{7R} \] 6. **Finding the Difference (λ_max - λ_min)**: \[ \lambda_{\text{max}} - \lambda_{\text{min}} = \frac{144}{7R} - \frac{9}{R} \] Taking a common denominator (7R): \[ = \frac{144 - 63}{7R} = \frac{81}{7R} \] 7. **Substituting the Value of R**: From the Lyman series, we know that: \[ \frac{1}{R} = 340 \text{ Å} \] Thus, \[ R = \frac{1}{340} \text{ Å}^{-1} \] Substituting this into the equation: \[ \lambda_{\text{max}} - \lambda_{\text{min}} = \frac{81}{7 \cdot \frac{1}{340}} = \frac{81 \cdot 340}{7} \] Calculating this gives: \[ \lambda_{\text{max}} - \lambda_{\text{min}} = \frac{27540}{7} \approx 3934.29 \text{ Å} \] ### Final Answer: The difference between the maximum and minimum wavelengths for the Paschen series is approximately **3934.29 Å**.
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