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Given i) A harr B+C K(eq)(1) ii) B+C...

Given
`i) A harr B+C K_(eq)(1)
ii) B+C harr P K_(eq)(2)`
then `K_(eq)` for reaction `Aharrp`is

A

`K_(eq)(1).K_(eq)(2)`

B

`K_(eq)(1)//K_(eq)(2)`

C

`K_(eq)(1)+K_(eq)(2)`

D

`K_(eq)(1)-K_(eq)(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant \( K_{eq} \) for the reaction \( A \rightleftharpoons P \), we will use the given equilibrium constants for the two reactions provided. ### Step 1: Write down the given reactions and their equilibrium constants. 1. For the reaction \( A \rightleftharpoons B + C \), the equilibrium constant is given as: \[ K_{eq1} = \frac{[B][C]}{[A]} \] 2. For the reaction \( B + C \rightleftharpoons P \), the equilibrium constant is given as: \[ K_{eq2} = \frac{[P]}{[B][C]} \] ### Step 2: Rearrange the equations to express concentrations. From the first equilibrium constant \( K_{eq1} \): \[ [B][C] = K_{eq1} [A] \] From the second equilibrium constant \( K_{eq2} \): \[ [B][C] = \frac{[P]}{K_{eq2}} \] ### Step 3: Equate the expressions for \( [B][C] \). Since both expressions equal \( [B][C] \), we can set them equal to each other: \[ K_{eq1} [A] = \frac{[P]}{K_{eq2}} \] ### Step 4: Solve for \( K_{eq} \) for the reaction \( A \rightleftharpoons P \). Rearranging the equation gives: \[ [P] = K_{eq1} [A] K_{eq2} \] Now, we can express the equilibrium constant \( K_{eq} \) for the reaction \( A \rightleftharpoons P \): \[ K_{eq} = \frac{[P]}{[A]} = \frac{K_{eq1} [A] K_{eq2}}{[A]} \] This simplifies to: \[ K_{eq} = K_{eq1} \cdot K_{eq2} \] ### Final Answer: Thus, the equilibrium constant \( K_{eq} \) for the reaction \( A \rightleftharpoons P \) is: \[ K_{eq} = K_{eq1} \cdot K_{eq2} \] ---
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