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In 100ml , 0.1N Na2CO3.xH2O solution. Ma...

In 100ml , 0.1N `Na_2CO_3.xH_2O` solution. Mass of solute is 1.43g, then value of X is:

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To find the value of \( x \) in the compound \( Na_2CO_3 \cdot xH_2O \), we will follow these steps: ### Step 1: Calculate the number of equivalents The number of equivalents can be calculated using the formula: \[ \text{Number of equivalents} = \text{Normality} \times \text{Volume in liters} \] Given: - Normality (N) = 0.1 N - Volume = 100 ml = 0.1 L (since 1000 ml = 1 L) So, \[ \text{Number of equivalents} = 0.1 \, \text{N} \times 0.1 \, \text{L} = 0.01 \, \text{equivalents} \] ### Step 2: Relate equivalents to moles The number of equivalents is also related to the number of moles and the valency factor. For \( Na_2CO_3 \), the valency factor is 2 (as it dissociates into 2 sodium ions and 1 carbonate ion). Using the formula: \[ \text{Number of equivalents} = \text{Number of moles} \times \text{Valency factor} \] Let \( n \) be the number of moles: \[ 0.01 = n \times 2 \] Thus, \[ n = \frac{0.01}{2} = 0.005 \, \text{moles} \] ### Step 3: Use the number of moles to find the molecular weight We know that: \[ \text{Number of moles} = \frac{\text{Mass}}{\text{Molecular weight}} \] Given mass of solute = 1.43 g, we can write: \[ 0.005 = \frac{1.43}{\text{Molecular weight}} \] Rearranging gives: \[ \text{Molecular weight} = \frac{1.43}{0.005} = 286 \, \text{g/mol} \] ### Step 4: Calculate the molecular weight of \( Na_2CO_3 \cdot xH_2O \) The molecular weight of \( Na_2CO_3 \) is calculated as follows: - Sodium (Na) = 23 g/mol, so \( 2 \times 23 = 46 \) g/mol - Carbon (C) = 12 g/mol - Oxygen (O) = 16 g/mol, so \( 3 \times 16 = 48 \) g/mol Thus, the molecular weight of \( Na_2CO_3 \) is: \[ 46 + 12 + 48 = 106 \, \text{g/mol} \] Now, including the water of hydration: \[ \text{Molecular weight of } Na_2CO_3 \cdot xH_2O = 106 + 18x \] ### Step 5: Set up the equation Now we can set up the equation: \[ 106 + 18x = 286 \] ### Step 6: Solve for \( x \) Rearranging gives: \[ 18x = 286 - 106 \] \[ 18x = 180 \] \[ x = \frac{180}{18} = 10 \] ### Conclusion Thus, the value of \( x \) is: \[ \boxed{10} \]
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