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After np orbitals are filled, the next o...

After np orbitals are filled, the next orbital filled will be :-

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While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but reverse happens during the ionisation of the atom. Explain why?

While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but reverse happens during the ionisation of the atom. Explain why?