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Which one of the following is incorrect ...

Which one of the following is incorrect for ideal solution?

A

`Delta H_(mix)=0`

B

`Delta U_(mix)=0`

C

`Delta P=P_(obs.)-P_("calculated by Raoult's law")=0`

D

`Delta G_(mix)=0`

Text Solution

Verified by Experts

The correct Answer is:
D

Key Idea - For this problem, the following expression can be used.
`Delta G_("mix")=Delta H_("mix")-T Delta S_("mix")`
For an ideal gas
`Delta H_("mix")=0, Delta U_("mix")=0, Delta S_("mix")ne 0`
Putting all these values in the expression.
`Delta G_("mix")=Delta H_("mix")-T Delta S_("mix")rArr Delta G_("mix")=0-T Delta S_("mix")`
`therefore Delta G_("mix")ne 0`
Thus, option (d) is incorrect.
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