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Consider the following reactions: (i) ...

Consider the following reactions:
(i) `H^(+)(aq)+OH^(-)(aq)rarrH_(2)O(l)` ,
`DeltaH==-X_(1)Kjmol^(-1)`
(ii) `H_(2)(g)+(1)/(2)O_(2)(g)rarrH_(2)O(l),DeltaH=-X_(2)Kjmol^(-1)`
(iii) `CO_(2)(g)+H_(2)(g)rarrCO(g)+H_(2)O(l)` ,
`DeltaH=-X_(3)KJmol^(-1)`
(iv) `C_(2)H_(2)(g)+(5)/(2)O_(2)(g)rarr2CO_(2)(g)+H_(2)O(l)` ,
`DeltaH=+X_(4)KJmol^(-1)`
Enthanlpy of formation of `H_(2)O(l)` is

A

`-x_(2) KJ "mol"^(-1)`

B

`+x_(3) KJ "mol"^(-1)`

C

`-x_(4) KJ "mol"^(-1)`

D

`+x_(1) KJ "mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

Enthalpy of formation : The amount of heat evolved or absorbed during the formation of 1 mole of a compound from its constituent elements is known as heat of formation So, the correct answer is
`H_(2)(g)+(1)/(2)O_(2)(g) to H_(2)O(l)` ,
`DeltaH=-x_(2) KJ "mol"^(-1)`
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