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Which one of the following chargcterisit...

Which one of the following chargcterisitic is associated with adsorption?

A

`DeltaG, DeltaH` and `DeltaS` all are negative

B

`DeltaG` and `DeltaH` are negative but `DeltaS` is positive

C

`DeltaG` and `DeltaS` are negative but `DeltaH` is positive

D

aqueous solution of slaked lime

Text Solution

Verified by Experts

The correct Answer is:
A

Adsorption is a spontaneous process that occurs with release in energy and decrease in the randomness (i.e. entropy) of the adsorbed substance. For a spontaneous process. `DeltaG` must be negative
`DeltaG = DeltaH - TDeltaS`
As the process is exothermic and randomness of molecule (entropy) decreases hence, both `DeltaH` and `DeltaS` will be negative as well.
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