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Pick out the correct statement with respect to `[Mn(CN)_(6)]^(3-)`:

A

It is `sp^(3)d^(2)` hybridised and octahedral

B

It is `sp^(3)d^(2)` hybridised and tetrahedral

C

It is `d^(2)sp^(3)` hybridised and octahedral

D

It is `dsp^(2)` hybridised and square planar

Text Solution

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The correct Answer is:
C

`[Mn(CN)_(6)]^(3-)` is `d^(2)sp^(3)`- hybridised and octahedral complex. In `[Mn(CN)_(6)]^(3-)`, Mn is in +3 oxidation state
`Mn^(3+)=3d^(4)4s^(0)`
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NEET PREVIOUS YEAR (YEARWISE + CHAPTERWISE)-COORDINATION COMPOUNDS-EXERCISE
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  2. Correct increasing order for the wavelengths of absorption in the visi...

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  3. Pick out the correct statement with respect to [Mn(CN)(6)]^(3-):

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  4. Which of the following has longest C-O bond length? (Free C-O bond len...

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  5. Which of the following pairs of d-orbitals will hare electron density ...

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  6. The correct increasing order of trans-effect of the following species ...

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  7. Jahn - Teller effect is not observed in high spin complexes of

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  8. Cobalt (III) chloride forms several octahedral complexes with amonia. ...

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  9. Which of these statements about [Co(CN)6]^(3-) is true?

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  10. Number of possible isomer for the complex [Co(en)(2)CI(2)]CI will be: ...

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  11. The hybridization involved in complex [Ni(CN)(4)]^(2-) is (At. No . Ni...

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  12. The sum of coordination number and oxidation number of the metal M in ...

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  13. The name of complex ion, [Fe(CN(6))]^(3-) is

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  14. Among the following complexes, the one which shows zero crystal field ...

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  15. The complex used as an anticancer agent is

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  16. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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  17. Which one of the following is an outer orbital complex and exhibits pa...

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  18. Of the following complex ions, which is diamagnetic in natures?

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  19. The complex [Co(NH(3))(6)][Cr(CN)(6)]" and "[Cr(NH(3))(6)][Co(CN)(6)] ...

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  20. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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