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Which of the following complex ions is e...

Which of the following complex ions is expected to absorb visible light?

A

`[Sc(H_(2)O)_(3)(NH_(3))_(3)]^(3+)`

B

`[Ti(en)_(2)(NH_(3))_(2)]^(4+)`

C

`[Cr(NH_(3))_(6)]^(3+)`

D

`[Co(en)_(3)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

In `[Cr(NH_(3))_(6)[^(3+),Cr" is present as "Cr^(3+), Cr^(3+)=[Ar]3d^(3), 4s^(0)`

Since, this complex has three unpaired electrons, excitation of electrons is possible and thus, it is expected that this complex will absorb visible light.
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NEET PREVIOUS YEAR (YEARWISE + CHAPTERWISE)-COORDINATION COMPOUNDS-EXERCISE
  1. The existence of two different coloured comlexes with the composition ...

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  2. Amongst [TiE(6)]^(2-), [CoF(6)]^(3-), Cu(2)Cl(2) and [NiCl(4)]^(2-) [A...

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  3. Which of the following complex ions is expected to absorb visible ligh...

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  4. Which of the following does not show optical isomerism ?

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  5. In which of the following coordination entites the magnitude of Delta(...

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  6. Which of the following complexes exhibits the highest paramagnetic beh...

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  7. Which of the following will give a pair of enontiomorphs ? en = NH(2...

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  8. The d electron congfiguration of Cr^(2+) , Mn^(2+) , Fe^(2+) and Ni^(2...

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  9. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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  10. [Co(NH(3))(4)(NO(2))(2)]CI exhibits

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  11. Which one of the following is expected to exhibit optical isomerism (e...

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  12. Which of the following is an inner orbital complex as well as diamagne...

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  13. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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  14. Considering H2O as a weak field ligand, the number of unpaired electro...

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  15. CN^(-) is a strong field ligand. This is due to the fact that

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  16. Which of the following does not have a metal carbon bond?

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  17. Which of the following is considered to be an anticancer species?

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  18. Which of the following coordination compounds would exhibit optical is...

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  19. Among the following, which is not the pi-bonded organometallic compoun...

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  20. The number of unpaired electrons in the complex ion [CoF(6)]^(3-) is

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