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Which one of the following is expected t...

Which one of the following is expected to exhibit optical isomerism (en=ethylenediamine)?

A

`Cis-[Pt(NH_(3))_(2)Cl_(2)]`

B

`Trans-[Co(en)_(2)Cl_(2)]^(+)`

C

`Trans-[Pt(NH_(3))_(2)Cl_(2)]`

D

`Cis-[Co(en)_(2)Cl_(2)]^(+)`

Text Solution

Verified by Experts

The correct Answer is:
D

`Cis-[Co(en)_(2)Cl_(2)]^(+)` is able to show the phenomenon of optical isomerism because it can form a superimposable mirror image.

It gives super imposable structure but trans-form is optically inactive
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NEET PREVIOUS YEAR (YEARWISE + CHAPTERWISE)-COORDINATION COMPOUNDS-EXERCISE
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  2. [Co(NH(3))(4)(NO(2))(2)]CI exhibits

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  3. Which one of the following is expected to exhibit optical isomerism (e...

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  4. Which of the following is an inner orbital complex as well as diamagne...

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  5. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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  6. Considering H2O as a weak field ligand, the number of unpaired electro...

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  7. CN^(-) is a strong field ligand. This is due to the fact that

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  8. Which of the following does not have a metal carbon bond?

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  9. Which of the following is considered to be an anticancer species?

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  10. Which of the following coordination compounds would exhibit optical is...

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  11. Among the following, which is not the pi-bonded organometallic compoun...

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  12. The number of unpaired electrons in the complex ion [CoF(6)]^(3-) is

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  13. According to IUPAC nomenclature sodium nitroprusside is named as

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  14. Which of the following octahedral complex does not show geometrical is...

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  15. The hypothetical complex chloro diaquatriammine cobalt (II) chloride c...

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  16. Atomic numbers of Cr and Fe are respectively 24 and 26. Which of the f...

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  17. Which of the following will give maximum number of isomer ?

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  18. Which of the following organometallic compound is a sigma and pi bonde...

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  19. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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  20. Which statement is incorrect?

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