Home
Class 12
CHEMISTRY
Borane is an electron deficient compound...

Borane is an electron deficient compound. It has only six valence eletons, so the boron atom lacks an octet. Acquiring an octet is the driving force for the unusual bonding structure found in boron compounds. As an electron deficient compound, `BH_(3)` is a strong electrophile, capable of adding to a double bond. This hydroboration of double bond is though to oC Cur in one step, with the boron atom adding to the less highly substituted end of the double bond. In transition state, the boron atom withdraws electrons from the pi bond and the carbon at theother end of the double bond acquires a partial positive charge. This positive charge is more stable on the more highly subsituted carbon atom. The second step is the oxidation of boron atom, removing it from carbon and replacing it with hydroxyl group by using `H_(2)O_(2)//OH^(bar(..))`.
The simultaneous addition of boron and hydrogen to the double bond leads to a syn addition. Oxidation of the trialkyl borane replaces boron with a hydroxyl group in the same stereochemical position. Thus, hydroboration of alkenen is an example of steropecific reaction, in which different steroisomers of starting compounds react to give different steroisomers of the product.
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH=CH_(2)` `underset((ii)H_(2)O_(2)//OH^(bar(..)))overset((i)BH_(3)//THF)rarrZ`.
`Z` is :

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • ALKENE, ALKANE & ALKYNE

    ALLEN|Exercise EXERCISE-4(A)|10 Videos
  • ALKENE, ALKANE & ALKYNE

    ALLEN|Exercise EXERCISE-4(B)|10 Videos
  • ALKENE, ALKANE & ALKYNE

    ALLEN|Exercise EXERCISE-1|119 Videos
  • AIIMS 2019

    ALLEN|Exercise CHEMISTRY|35 Videos
  • ALKYL AND ARYL HALIDE

    ALLEN|Exercise EXERCISE-05 (B)|37 Videos

Similar Questions

Explore conceptually related problems

Borane is an electron deficient compound. It has only six valence eletons, so the boron atom lacks an octet. Acquiring an octet is the driving force for the unusual bonding structure found in boron compounds. As an electron deficient compound, BH_(3) is a strong electrophile, capable of adding to a double bond. This hydroboration of double bond is though to oC Cur in one step, with the boron atom adding to the less highly substituted end of the double bond. In transition state, the boron atom withdraws electrons from the pi bond and the carbon at theother end of the double bond acquires a partial positive charge. This positive charge is more stable on the more highly subsituted carbon atom. The second step is the oxidation of boron atom, removing it from carbon and replacing it with hydroxyl group by using H_(2)O_(2)//OH^(bar(..)) . The simultaneous addition of boron and hydrogen to the double bond leads to a syn addition. Oxidation of the trialkyl borane replaces boron with a hydroxyl group in the same stereochemical position. Thus, hydroboration of alkenen is an example of steropecific reaction, in which different steroisomers of starting compounds react to give different steroisomers of the product. Find the product of following reaction

BCl_(3) is an electron-deficient compound.

Which one is the electron deficient compound ?

Why boron forms electron deficient compounds?

Boron form covalent compound due to

Which one of following is not an electron deficient compound

If diborane each boron has three electrons bonds around each B atom and form

ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-3
  1. X(C(4)H(9)Br) underset(Delta) overset(alc.KOH)to Yoverset(Br(2)//"CC"l...

    Text Solution

    |

  2. X(C(4)H(9)Br) underset(Delta) overset(alc.KOH)to Yoverset(Br(2)//"CC"l...

    Text Solution

    |

  3. Borane is an electron deficient compound. It has only six valence elet...

    Text Solution

    |

  4. Borane is an electron deficient compound. It has only six valence elet...

    Text Solution

    |

  5. Borane is an electron deficient compound. It has only six valence elet...

    Text Solution

    |

  6. Borane is an electron deficient compound. It has only six valence elet...

    Text Solution

    |

  7. Borane is an electron deficient compound. It has only six valence elet...

    Text Solution

    |

  8. Hydrocarbon (A) C(6)H(10), on treatment with H(2)//Ni, H(2)/ Lindlar's...

    Text Solution

    |

  9. Hydrocarbon (A) C(6)H(10) on treatment with H(2)/Ni, H(2)//Lindlar's c...

    Text Solution

    |

  10. Hydrocarbon (A) C(6)H(10) on treatment with H(2)/Ni, H(2)//Lindlar's c...

    Text Solution

    |

  11. Statement-I : In nitration H(2)SO(4) is used as sulphonating agent. ...

    Text Solution

    |

  12. Statement-I : C(6)H(5) is a meta-directing group. Because Statemen...

    Text Solution

    |

  13. Assertion : Tropylium cation is aromatic in nature Reason : The only...

    Text Solution

    |

  14. Statement-I : Benzene on heating with conc. H(2)SO(4) gives benzene su...

    Text Solution

    |

  15. Statement-I : Chlorination of ethyl benzene with Cl(2) in prescence of...

    Text Solution

    |

  16. Statement-I : Nitration of toluene is easier than benzene Because ...

    Text Solution

    |

  17. Statement-I : Benzene reacts with n-propyl chloride in presence of AlC...

    Text Solution

    |

  18. Statement-II : Most o-,P-directing substitution are deactivating. Be...

    Text Solution

    |

  19. Statement-I : Nitrobenzene does not undergo Friede1-Craft's reaction. ...

    Text Solution

    |

  20. Statement-I : The rate of nitration of benzene is less than hexa deute...

    Text Solution

    |